PENGARUH RASIO MOL, SUHU DAN LAMA REAKSI TERHADAP BILANGAN IOD, BILANGAN ASAM, BILANGAN PEROKSIDA DAN KANDUNGAN SULFONAT SURFAKTAN DARI CPO

Authors

  • Sri Hidayati
  • Illim -

DOI:

https://doi.org/10.25077/jrk.v2i2.155

Abstract

 

ABSTRACT

 

A surfactant is a surface-active agent that can be produced by chemical or biochemical synthesis.  The main characteristic of a surfactant is having polar and non polar groups at the same molecule (amphiphilic molecules) and forming head-tail configuration. This research as aimed to obtain      the optimum condition (reaction temperature, sulphonation reaction and molar ratio)                              of sulphonation process in producing MES from CPO methyl ester and to investigate                          the characteristic of MES produced. Measurements conducted include iodine value, acid value, peroxide value and absorbance of Sulfonate. Experimental design used was Response Surface Method (RSM) and Central Composite Design (CCD) with three factors. MES resulted from this best condition   had following characteristic or CPO was obtained with ratio of reactants of 1:1.5, reaction time of 4.5 hour and reaction temperature of 108.9ºC with Acid value of 13.32 mg KOH/g sample, Iod value  of 41.12 Iod g/100 sample, Peroxide value of 7.6 mmole/1000 g, sulfonat absorbance of 0.76 AU.

 

Keywords :  metil ester sulfonat, acid value, iod value, peroxide value

 

   

Author Biographies

Sri Hidayati

   

Illim -

   

References

E. Hambali, A. Suryani, D. Haryadi, H. Hanafie, I. K. Reksowardoyo, M. Rivai, M. Ihsanur, P. Suryadarma, S. Tjitrosemito, T. H. Soerawidjaja, T. Pawitasari, T. Praksoso, dan W. Purnama, Jarak pagar tanaman penghasil biodiesel, Swadaya, 2006, 147.

W. B. Sheats, dan B. W. Mac Arthur, Methyl Ester Sulfonate Products, [terhubung berkala, http://www.chemithon.com,(26/2/2003).

C. Foster, Sulfonation and Sulfation Processes. In : Soap and Detergents, A Theoretical and Practical Review, Spitz, L, JAOCS., Champaign, Illinois, (1996).

J. Pore, Oil and Fat Manual, Intercept Ltd, Andover, UK, Paris, New York, 1993.

A. E. Sherry, B. E. Chapman, M. T. Creedon, J. M. Jordan, dan R. L. Moese, Nonbleach Process for the Purification of Palm C16-18 Methyl Ester Sulfonates, J. Am. Oil Chem., 72(7): 835-841, (1995).

AOAC, Official Method of Analysis of the Association of Official Analytical Chemist, AOAC, Washington, 1995.

J. B. Moreno, dan J. L Berna, Influence of Sulfonated Material and Its Sulfone Content on the Physical Properties of Linier Alkyl Benzene Sulfonates, JAOCS., 65(6), (1988).

P. C. Hu, dan M. E. Tuvell, Effect of Water Hardness Ions on the Solution Properties of an Anionic Surfactant, JAOCS., 65(8), (1988).

P. C. Hu, dan M. E. Tuvell, A Mechanistic Approach to the Thermal Degradation of α Olefin Sulfonates, JAOCS., 65(6), (1988).

Dunn, Effect of Oxidation Under Accelerated Conditions on Fuel Properties of Methyl Soya (biodiesel), JAOCS., 79(9), (2002).

R. M. Silverstein, and F. X Webster,. Spectrometric Identification Organic Compound, John Willey & Sons, Inc, New York, 1988.

S. M. Mukherji, S. P Singh dan R. P Kapoor, Organic Chemistry, 2, New Age International, Limited Publ, New Dehli, 1985.

R. L. Peesok, L. D Shields, T. Courns dan I. G. Mac William, Modern Method of Chemical Analysis, 2nd Editian, John Willey & Sons, Inc, New York, 1976.

Downloads

Published

2015-02-12

How to Cite

Hidayati, S., & -, I. (2015). PENGARUH RASIO MOL, SUHU DAN LAMA REAKSI TERHADAP BILANGAN IOD, BILANGAN ASAM, BILANGAN PEROKSIDA DAN KANDUNGAN SULFONAT SURFAKTAN DARI CPO. Jurnal Riset Kimia, 2(2), 148. https://doi.org/10.25077/jrk.v2i2.155

Issue

Section

Articles

Citation Check