DEGRADASI SENYAWA PERMETRINDENGAN MENGGUNAKAN TiO2-Anatase DAN ZEOLIT ALAM SECARA SONOLISIS

Authors

  • Zilfa -
  • Hamzar Suyani
  • Safni -
  • Novesar Jamarun

DOI:

https://doi.org/10.25077/jrk.v2i2.162

Abstract

 

 

ABSTRACT

 

The research about the degradation of permethryn compound had been done by sonolysis method using anatase- TiO2 and natural zeolyte (mordenit kinds) as catalysts. Permethryn is one of synthetic pyretroid pesticides that low toxicity for mamals but it is high toxicity for fishs, insects and water microorganisms. Sonolysis method is conducted by using ultrasonic wave at frequency 45 kHz. The results show that sonolysis method without the addition of anatase-TiO2 and zeolite on optimum temperature at 40°C during 120 minutes treatments could be degrade 20 mg/L permethryn until 22.23%. In other hands, the degradation of 20 mg/L permethryn in the same condition with adding 0.002 g anatase-TiO2 achieved 44.95% but for using 0.2 g zeolyte could be degrade 52.34%. 

 

Keywords :  degradation, permethrin ,TiO2-anatase , sonolysis, zeolite

   

Author Biographies

Zilfa -

   

Hamzar Suyani

   

Safni -

   

Novesar Jamarun

   

References

D. Setiawan, P. Handoko. Preparasi Katalis Cr/Zeolit Melalui Modifikasi Zeolit Alam FMIPA Jember.

E. Garcia, Validated HPLC methode for quantifying permethrin in parmaceutical formulation, J .Pharmaceutical, 24, (2001).

G. Tezcanly–Guyer, N. H. Ince Degradation and toxicity reduction of textile, J. Ultrasonic sonochemistry, 10: 235-240. (2003)

H. Lutnicka, Degradation of Pyrethroids in An Aquatic, J.Wat. Res., 33(16): 341-346, (1999).

H. Destaillats, Application of Ultrasound in NAPL, J.Environ. Sci. Technol., 35: 3019-3024, (2001).

Hiskia, Sonolytic, Photolytic, and Photocatalytic decomposition of Atrazine in the Presence of Polyoxometalates, J. Environ. Sci. Technol., 35: 2358-2364, (2001).

K. Munawir, Pemantauan Kadar Pestisida Organoklorin, J. Oseanologi dan Limnologi di Indonesia , 37: 13-23, (2005).

K. Tanaka, Improved Photocatalytic activity of Zeolit- and Silica- Incorporated TiO2, J. of Hazardous Materials B, 137: 947-951, (2006).

M. Chun Lu, Efect of Adsorbents Coated With Titanium Dioxide On The Photocatalytic Degradation Of Propoxur, J. Chemosphere, 38(3): 617-627, (1999).

M. B. Kasiri, Degradation of Acid Blue 74 using Fe-ZSM5 Zeolite as a heterogeneous photo-Fenton Catalyst, J. Applied Catalysis B: Environmental, 84 9-15, (2008).

Downloads

Published

2015-02-12

How to Cite

-, Z., Suyani, H., -, S., & Jamarun, N. (2015). DEGRADASI SENYAWA PERMETRINDENGAN MENGGUNAKAN TiO2-Anatase DAN ZEOLIT ALAM SECARA SONOLISIS. Jurnal Riset Kimia, 2(2), 140. https://doi.org/10.25077/jrk.v2i2.162

Issue

Vol. 2 No. 2 (2009): March

Section

Articles

Citation Check

License

Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.

1. License

The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License. 

2. Author(s)' Warranties

The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).

3. User Rights

Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.

4. Rights of Authors

Authors retain all their rights to the published works, such as (but not limited to) the following rights;

  • Copyright and other proprietary rights relating to the article, such as patent rights,
  • The right to use the substance of the article in own future works, including lectures and books,
  • The right to reproduce the article for own purposes,
  • The right to self-archive the article,
  • The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.

5. Co-Authorship

If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.