SINTESIS SURFAKTAN METIL ESTER SULFONAT DARI PALM OIL METHYL ESTER DAN NATRIUM METABISULFIT DENGAN PENAMBAHAN KATALIS KALSIUM OKSIDA

Authors

  • Nirwana - Jurusan Teknik Kimia Fakultas Teknik Universitas Riau, Indonesia
  • Irdoni -
  • Jatikta Yuniharti

DOI:

https://doi.org/10.25077/jrk.v8i2.229

Keywords:

methyl ester, methyl ester sulfonate, sulfonated, surfactant

Abstract

The most widely used surfactant is an anionic surfactant which is synthesized from petroleum namely Linear Alkylbenzene sulphonate (LABS). Methyl Ester Sulfonate which is currently being developed. Surfactant can produced from palm oil methyl ester via sulfonation sulfonate. When in this research using sodium metabisulphite. The aims of this work is to synthesize Methyl Ester Sulfonate surfactant from Palm Oil Methyl Ester using Sodium Metabisulphite and a catalyst Calcium Oxide. The effects of time and the mole ratio are also investigated. Sulfonation process carried out in 4, 5, 6 hours with mole ratio of 1: 0,5, 1:1, 1: 1,5, temperature of 80° C and with stirring speed of 450 rpm. It haven been found that the surfactant produced has density of (0.89490 g/cm3 - 0.89545 g/cm3), viscosity (2.0323 cP - 2.1329 cP), pH (2,03 - 2,48), surface tension (32.60 mN/m - 33.60 mN/m), interfacial tension (30.45 mN/m - 30.94 mN/m), and the stability emulsion (59.17% - 89, 17%).

References

Hapsari, M. 2003. Kajian pengaruh suhu dan kecepatan pengadukan pada proses produksi surfaktan dari metil ester minyak inti sawit dengan metode sulfonasi. Thesis. IPB: Bogor

Chasani, M., V.H. Nursalim., S. Widyaningsih., I.N. Budiasih., dan M.A Kurniawan. 2014. Sintesis, Pemurnian dan Karakterisasi Metil Ester Sulfonat (MES) sebagai Bahan Inti Deterjen dari Minyak Biji Nyamplung. Molekul.Vol.9: 63-72

Sulastri, Y. 2010. Sintesis Methyl Ester Sulfonic Acid (MESA) dari Crude Palm Oil (CPO) menggunakan Single Tube Falling Film reaktor. Thesis. IPB: Bogor

Hidayati, S. 2009. Pengaruh Rasio Mol, Suhu dan Lama Reaksi terhadap Tegangan Permukaan dan Stabilitas Emulsi Metil Ester Sulfonat Dari CPO. Jurnal Teknologi Industri dan Hasil Pertanian. Vol.14:38-44

Helianty, S dan Zulfansyah. 2011. Pembuatan Ester metilsulfonat dari ester metil Palm Stearin. Jurnal Teknobiologi. Vol.II: 37 – 39

Ebbing, D.D dan M.S Wringhton. 1990. General Chemistry. 3 rd Edition. Wilmington-USA: Houghton Mifflin Company

Foster, N.C. 1996. Sulfonation and Sulfation Processes. In: Spitz, L. (Ed). Soap and Detergents: A Theoretical and Practical Review. AOCS Press, Champaign, Illinois

American Society for Testing and Material (ASTM). 2001. Annual Book of ASTM Standards: Soap and Other Detergent, Polishes, Leather, Resilient Floor Covering. Baltimore: ASTM. PP 915-919

Sheats, W.B dan B.W MacArthur. 2002. Methyl Ester Sulphonate Products: The Chemithon Corporation, USA

Adiandri, R.S. 2006. Kajian Pengaruh Konsentrasi Metanol dan Lama Reaksi pada proses Pemurnian Metil Ester Sulfonat terhadap Karakteristik Detergen Bubuk. Thesis. IPB: Bogor

Pore, J. 1993. Oils and Fat Manual. Intercept Ltd, Andover, Uk, Paris :New York

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Published

2016-09-13

How to Cite

-, N., -, I., & Yuniharti, J. (2016). SINTESIS SURFAKTAN METIL ESTER SULFONAT DARI PALM OIL METHYL ESTER DAN NATRIUM METABISULFIT DENGAN PENAMBAHAN KATALIS KALSIUM OKSIDA. Jurnal Riset Kimia, 8(2), 125. https://doi.org/10.25077/jrk.v8i2.229

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