STUDI HANTARAN LISTRIK SENYAWA SRN+1TINO3N+1 (N = 1 DAN 2) FASA RUDDLESDEN-POPPER YANG DISINTESIS DENGAN METODE LELEHAN GARAM

Authors

  • Yulia Eka Putri Laboratorium Kimia Material Jurusan Kimia FMIPA, Universitas Andalas
  • Hamsal Yusri Laboratorium Kimia Material Jurusan Kimia FMIPA, Universitas Andalas
  • Hamsal Yusri Laboratorium Kimia Material Jurusan Kimia FMIPA, Universitas Andalas
  • Zulhadjri - Laboratorium Kimia Material Jurusan Kimia FMIPA, Universitas Andalas
  • Zulhadjri - Laboratorium Kimia Material Jurusan Kimia FMIPA, Universitas Andalas

DOI:

https://doi.org/10.25077/jrk.v8i2.237

Keywords:

Ruddlesden-Popper phase, thermoelectric, electrical conductivity, molten salt method.

Abstract

Srn+1TinO3n+1 (n = 1, 2,...n)Ruddlesden-Popper phase is a metal oxide compound with a layered structure consisting of SrTiO3 perovskite layers and strontium oxide (SrO) layers, thus this material has a potential as termoeletrik compounds that could be developed as an alternative material for renewable energy. In this study, we examine one of the 3 parameters of termoelectric properties, namely the electrical conductivity. Srn+1TinO3n+1 (n = 1 and 2)Ruddlesden-Popper phases were synthesized using molten salt method. The synthesis was carried out at 950 °C for 10 hours with a ratio of precursor and salt were 1: 0.5. Structural analysis by X-Ray Diffractometer (XRD) confirmed that all synthesized compounds formed Srn+1TinO3n+1 (n = 1, and 2) Ruddlesden-Popper phase with the characteristic peaks at 2q = 31o, 32o, and 46o. The morphology analysis by Scanning Electron Microscope (SEM) showed that the particles have plate-shaped with crystallites size were 20 nm. The electrical properties were measured using LCR meter with the highest electrical conductivity of 2.25x10-7 S / cm which showed the semiconductors behaviour.

References

G.A. Slack, CRC Handbook of Thermoelectrics, (Ed. D.M. Rowe) Boca Raton, FL: CRC Press, 1995, 407–440.

Y. Pei, X. Shi, A. LaLonde, H. Wang, G. Lidong Chen, and J. Snyder, Convergence of electronic bands for high performance bulk thermoelectrics, Nature, 473: 66 (2011).

C.L. Wan, Y.F. Wang, N. Wang, Y.E. Putri, W. Norimatsu, M. Kusunoki, and K. Koumoto, Modules, System and Application in Thermoelectrics, (Ed. D.M. Rowe), Boca Raton, FL: CRC Press, 2012, 4.1–4.11.

G.J. Snyder and E.S. Toberer, Complex thermoelectric materials, Nat. Mater. 7: 105 (2008).

T.M. Tritt, Thermoelectric phenomena, materials, and application, Annu. Rev. Mater. Res. 41: 433 (2011).

Ismunandar: Padatan Oksida Logam Struktur Sintesis dan Sifat-sifatnya., ITB., Bandung, (2006).

Ella. A.S., Arief. S., Zulhadjri. Z., Sintesis Fasa Aurivillius Lapis Empat SrBi4-XLaxTi4O15 Dengan Metode Lelehan Garam. Jurnal Kimia Unand 2:2, (2013).

Y.F.Wang., Lee.KH., Ohta.H., and Koumoto.K., Thermoelectric properties of electron doped SrO (SrTiO3) n ( n = 1 , 2 ) ceramics, J Applied Physics, 105: 103701, (2009).

Thoriyah, A., & Hamzah, F., Sintesis Oksida Perovskit La1-Xbaxcoo3-Δ dengan Metode Kopresipitasi Dan Karakterisasinya. Institut Teknologi Sepuluh November., 2009.

Elcombe,M.M.; Kisi, E.H.;Hawkins, K.D.; White, T.J.; Goodman, P.; Matheson, S., Structure determinations for Ca3Ti2O7, Ca4Ti3O10, Ca3.6Sr0.4Ti3O10 and a Refinement of Sr3Ti2O7., Philosophical Transactions of the Royal Society of London., (1991).

R. Jenkins and R.L. Snyder, Introduction to X-ray Powder Diffractometry, John Wiley & Sons Inc., 1996, 89-91.

Vengrenovich, R.D.; Gudyma, Yu. V.; Yarema, S. V., Ostwald ripening of quantum-dot nanostructures". Semiconductors, 35 (12),13781382, (2110).

Niu, Jian; Yan, Peng-xun; Seo, Won-Seon; Koumoto, Kunihito, Hydrothermal Synthesis of SrTiO3Nanoplates Through Epitaxial Self-Assembly of Nanocubes, Journal of Nanoscience and Nanotechnology, 12, 3, 2685-2690(6) (2012).

Irzaman, Erviansyah R, Syafutra H, Maddu A, dan Siswadi, Studi Konduktivitas Listrik Film Tipis Ba0.25Sr0.75TiO3 Yang Didadah Ferium Oksida (BFST) Menggunakan Metode Chemical Solution Deposition., Jurnal Berkala Fisika, 1410 – 96622010, 33 -38, (2010).

Hiromichi Ohta, SungWng Kim, Yoriko Mune, Teruyasu Mizoguchi, Kenji Nomura, Shingo Ohta, Takashi Nomura, Yuki Nakanishi, Yuichi Ikuhara, Masahiro Hirano, Hideo Hosono and Kunihito Koumoto, Giant thermoelectric Seebeck coefficient of a two-dimensional electron gas in SrTiO3, Nature Materials, 6, 129 - 134 (2007).

Y.E. Putri,Chunlei Wan, Feng Dang, Takao Mori, Yuto Ozawa, Wataru Norimatsu, Michiko Kusunoki and Kunihito Koumoto, Effects of Transition Metal Substitution on the Thermoelectric Properties of Metallic (BiS)1.2(TiS2)2 Misfit Layer Sulfate, Journal of Electronic Materials, 43, 6, (2014).

A. J. Katz and A. H. Thompson, Fractal Sandstone Pores: Implications for Conductivity and Pore Formation, Phys. Rev. Lett. 54: 1325 (1985).

Li Li Zhang and X. S. Zhao, Carbon-based materials as supercapacitor electrodes, Chem. Soc. Rev., 38: 2520-2531, (2009).

Downloads

Published

2015-03-19

How to Cite

Putri, Y. E., Yusri, H., Yusri, H., -, Z., & -, Z. (2015). STUDI HANTARAN LISTRIK SENYAWA SRN+1TINO3N+1 (N = 1 DAN 2) FASA RUDDLESDEN-POPPER YANG DISINTESIS DENGAN METODE LELEHAN GARAM. Jurnal Riset Kimia, 8(2), 176. https://doi.org/10.25077/jrk.v8i2.237

Issue

Section

Articles

Citation Check