Adsorpsi Asam Humat pada Zeolit Alam yang Dimodifikasi dengan TiO2

Authors

  • Upita Septiani Laboratorium Kimia Material, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Andalas, Indonesia http://orcid.org/0000-0002-1846-3105
  • Fiska Julian Tasari Laboratorium Kimia Material, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Andalas, Indonesia
  • Zilfa Zilfa Laboratorium Kimia Analitik, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Andalas, Indonesia

DOI:

https://doi.org/10.25077/jrk.v11i1.344

Keywords:

adsorption, humic acid, coating, sol-gel, zeolit/TiO2,

Abstract

This research modified natural zeolite with TiO2 synthesized by the sol-gel process which was applied as a humic acid adsorbent. The purpose of this study was to coat natural zeolites with TiO2 to increase the adsorption capacity of natural zeolites as humic acid adsorbents. The natural zeolite powders were obtained from Kabupaten Solok, West Sumatra, based on X-ray Fluorescence (XRF) analysis, the ratio of silica/alumina (Si/Al) was 4.35, indicating that natural zeolite was clinoptilolite zeolite. Scanning Electron Microscopy (SEM) analysis showed natural zeolite has a rough surface with closed pores while zeolite coated with TiO2 (zeolite/TiO2) has a homogeneous, smooth surface with open pore. The results of the Energy Dispersive X-Ray Spectroscopy (EDS) analysis showed that the level of TiO2 was 7.1%, this result showed that TiO2 has been coated on the surface of the zeolite. Natural zeolite and zeolite/TiO2 were applied as humic acid adsorbents. Maximum adsorption capacity of natural zeolites and zeolites/TiO2 were 0.2787 mg/g and 1.199 mg/g, respectively.

Author Biography

Upita Septiani, Laboratorium Kimia Material, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Andalas

Jurusan Kimia

References

Said, N. I., Kesehatan masyarakat dan teknologi peningkatan kualitas air. Direktorat Teknologi Lingkungan Deputi Bidang Teknologi INF, (1999).

Rahmawati, A., Isolasi dan karakterisasi asam humat dari tanah gambut. J. Phenom., 2(1): (2011).

Liu, S., Lim, M. & Amal, R., TiO2-coated natural zeolite: Rapid humic acid adsorption and effective photocatalytic regeneration. Chem. Eng. Sci., 105: 46–52 (2014).

Sun, D. D. & Lee, P. F., TiO2 microsphere for the removal of humic acid from water: Complex surface adsorption mechanisms. Sep. Purif. Technol., 91: 30–37 (2012).

Capone, D. G., Bronk, D. A., Mulholland, M. R. & Carpenter, E. J., Nitrogen in the marine environment. Elsevier, (2008).

Septiani, U., Putri, R. A. & Jamarun, N., Synthesis of zeolite ZMS-5 from rice husk ash ash as catalyst in vegetable oil transesterification for biodisel production. Der Pharm. Lett., 8(19): 86–91 (2016).

Septiani, U., Admi., Afriza, D. & Yefrida., Effect of cetyltrimethylammonium bromide (CTAB) template on synthesis of zeolitic material from fly ash and application of zeolitic material obtained as an adsorbent of heavy metals Cd and Cu. Res. J. Chem. Environ., 22(9): 23–26 (2018).

Muhammad, L. F., Pemanfaatan zeolit alam sumatera barat sebagai pendukung TiO2 dalam degradasi congo red serta simulasi limbah secara fotolisis. Universitas Andalas, (2016).

Las, T. & Zamroni, H., Penggunaan zeolit dalam bidang industri dan lingkungan. J. Zeolit Indones., 1(1): 27–34 (2002).

Liu, X., Liu, Y., Lu, S., Guo, W. & Xi, B., Performance and mechanism into TiO2/Zeolite composites for sulfadiazine adsorption and photodegradation. Chem. Eng. J., 350: 131–147 (2018).

Trivana, L., Sugiarti, A. & Rohaeti, E., Sintesis zeolit dan komposit seolit/TiO2 dari kaolin serta uji adsorpsi fotodegradasi biru metilena. AlChemy J. Penelit. Kim., 11(2): 147–162 (2015).

Alshameri, A., Yan, C. & Lei, X., Enhancement of phosphate removal from water by TiO2/Yemeni natural zeolite: Preparation, characterization and thermodynamic. Microporous Mesoporous Mater., 196: 145–157 (2014).

Downloads

Published

2020-03-30

How to Cite

Septiani, U., Tasari, F. J., & Zilfa, Z. (2020). Adsorpsi Asam Humat pada Zeolit Alam yang Dimodifikasi dengan TiO2. Jurnal Riset Kimia, 11(1), 43–51. https://doi.org/10.25077/jrk.v11i1.344

Issue

Vol. 11 No. 1 (2020): March

Section

Articles

Citation Check

License

Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.

1. License

The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License. 

2. Author(s)' Warranties

The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).

3. User Rights

Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.

4. Rights of Authors

Authors retain all their rights to the published works, such as (but not limited to) the following rights;

  • Copyright and other proprietary rights relating to the article, such as patent rights,
  • The right to use the substance of the article in own future works, including lectures and books,
  • The right to reproduce the article for own purposes,
  • The right to self-archive the article,
  • The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.

5. Co-Authorship

If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.