Penentuan Vanadium Secara Spektrofotometri Fosfowolfrovanadat Dalam Batuan Bukit Pianggu Kabupaten Solok

Authors

  • Roswita -
  • Hamzar Suyani
  • Safni -

DOI:

https://doi.org/10.25077/jrk.v2i1.96

Abstract

 

ABSTRACT

 

A simple, rapid and accurate Spectrophotometric method described to the determination of vanadium in ore using sodium tungstat as a complexing agent. The method is based on the oxidation of sodium tungstat to form a yellow colored on reaction with vanadium (V), having maximum an absorption occurred at 403 nm. The relative standar deviation of the method for 8 mg/L vanadium (n=11) was 0.24%, and the molar absorptivity is 2.026103 L mol-1cm-1 and sensitivity Sandell is 2.5  10-2 mg cm.2 . The recovery test is 99.47%.  The effect of ion interfering Fe  (element large amount in ore) on determination is describe. The general procedure which was developed is suittable for determination of 0-20 mg/L of Vanadium and should be applicable to variety of ore sample.

 

Keywords : vanadium, spectrophotometric, sodium tungstat, ore

Author Biographies

Roswita -

Hamzar Suyani

Safni -

References

R. S. Young, Chemical Analysis in Extractive Metallurgy, Griffin, London, 1971, 220-222.

T. N. Kumar, and H. D. Revanasiddappa, Spectrophotometric Determination of Vanadium Using Variamine Blue and its Applycation to Syntetic, Environmental and Biologycal samples, Iran.Chem., 2: 161-167, (2005).

U. Repinc, and L. Benedik, Determination of Vanadium In Dietary Suplements, Acta Chim., 51: 59-65, (2005).

D. W. Hastings, and S. R. Emerson, Determination of Picogram Quantities of Vanadium In Calcite and Seawater by Isotope Dilution Inductively Coupled Plasma Mass Spectrometry With Electrothermal Vaparization, Anal. Chem., 68: 371-377, (1996).

L. Yang, R. E. Sturgeon, D. Prince, and S. Gabos, Determination of Vanadium In Biologycal Fluids Using HR-ICP-MS, Anal. At . Spect., 17: 1300-1303, (2002).

G. Telep, and D. F. Boltz, Ultraviolet Spectrophotometric Determination of Vanadium, Anal. Chem., 23: 901-903, (1951).

Y. Nakamoto, T. Ishimaru, N. Endo, and K. Matsusaki, Determination of Vanadium in Heavy Oils by Atomic Absorption Spectrometry Using a Graphite Furnace Coated with Tungsten, Anal. Sci., 20: 739-741, (2004).

N. Acnihotri, R. Dass, and R. Mehta, A Highly Sensitive and Selective Spectrophotometric Determination of Vanadium(V) Using 6-Chloro-3-Hydroxy-7-methyl-2-(2-thienyl)- 4H-chromen-4-One, Anal. Sci., 15: 1261-1264, (1999).

R. Lobinski, and Z. Marczenko, Flotation-Spectrophotometric of Vanadium with 3,5-Dinitrocatechol and Rhodamine B, Anal.Sci., 4: 629-635, (1988).

A. M. Shiller, L. Mao, and J. Cramer, Determination of Dissolved Vanadium in Natural Waters by Flow Injection Analysis with Colorinetric Detection, Limnol. Oceanodr., 43(3): 526-529, (1998).

R. A. Day, and A. L. Underwood, Analisa Kimia Kuatitatif, terjemahan A. H Pudjaatmaka, 5, Erlangga, Jakarta, 1999.

A. I. Vogel, Kimia Analisis Kuantitatif Anorganik, terjemahan A. Hadyana dan L. Setiyono, 4, EGC, Jakarta, 1994.

Harmita, Petunjuk Pelaksanaan Validasi Metode dan Cara Perhitungannya, Majalah Ilmu Kefarmasian, 1(3): 117-135, (2004).

Anonim, Sebaran Deposit Bahan Tambang pada kecamatan IX Koto Sungai Lasi, Gunung Talang, Pantai Cermin, dan Lembah Gumanti Kabupaten Solok, Dinas Pertambangan dan Lingkungan Hidup, Solok (2004).

Downloads

Published

2015-02-11

How to Cite

-, R., Suyani, H., & -, S. (2015). Penentuan Vanadium Secara Spektrofotometri Fosfowolfrovanadat Dalam Batuan Bukit Pianggu Kabupaten Solok. Jurnal Riset Kimia, 2(1), 51. https://doi.org/10.25077/jrk.v2i1.96

Issue

Section

Articles

Citation Check