GRAFTING TEMBAGA(II) PADA SILIKA MODIFIKASI

Authors

  • Syukri -

DOI:

https://doi.org/10.25077/jrk.v4i2.116

Abstract

 

ABSTRACT

 

A copper(II) acetonitrile complex has been grafted on modified silica and characterized by Fouruer Transform Infra Red (FTIR) and Energy Dispersive X-ray (EDX). The succesful experiment was confirmed by the appearance of shifted CN stretching vibration of acetonitrile on modified silica surface (FTIR analysis). The amount of copper(II) loaded by the silica was of ~ 7 % proven by EDX measurement. 

 

Key words: Grafting process, modified silica, metal loading

 

References

X. S. Zhao, X. Ying Bao, Wanping Guo, and Fang Yin Lee, Amobilizing Catalysts on Porous Materials, Materials Today, Vol. 9, No. 3, p. 32 (2006).

H. U. Blaser, A. Indolese, and A. Schnyder, Applied Homogeneous Catalysis by Organometallic Complexes, Current Science, Vol. 78, No. 11, p. 1336 (2000).

C. E. Housecroft, , A. G. Sharpe, Inorganic Chemistry, 2nd ed., Pearson Prentice Hall (2005)

Syukri, A. K. Hijazi, A. Sakthivel, A. I. Al-Hmaideen and F. E. Kühn, Heterogenization of Solvent-Ligated Copper(II) Complexes on Poly(4-Vinylpyridine) for the Catalytic Cyclopropanation of Olefins, Inorganica Chimica Acta, 360, p. 197 (2007)

C. Sumate, S. Chavadej, E. Gulari, Borane-Functionalized Silica Supports In Situ Activate Heterogenoeus Zirconocene Catalysts for MAO-Free Ethylene Polymerization, Journal of Molecular Catalysis, 185, p. 167 (2002)

P.K. Jal, S. Patel, B.K. Mishra, Chemical Modification of Silica Surface by Amobilization of Functional Groups for Extractive Concentration of Metal Ions, Talanta, 62, p. 1005 (2004).

M. P. Price, James H. Clark and Duncan J. Macquarrie, Modified Silicas for Clean Technology, J. Chem. Soc., Dalton Trans., p. 101 (2000)

X. S. Zhao, X. Ying Bao, Wanping Guo, and Fang Yin Lee, Amobilizing Catalysts on Porous Materials, Materials Today, Vol. 9, No. 3, p. 32 (2006)

Syukri, C. E. Fischer, A. I. Al-Hmaideen, Yang Li, Ying Zheng, F. E. Kühn, Modified MCM-41-Supported Acetonitrile Ligated Copper(II) and its Catalytic Activity in Cyclopropanation of Olefins, Microporous and Mesoporous Materials, 113, p. 171 (2008).

A. Sakthivel. S. Syukri, A. K. Hijazi and F. E. Kühn, Heterogenization of [Cu(NCCH3)6][BF4]2 on mesoporous AlMCM-41/AlMCM-48 and its Application as Cycloproponation Catalyst, Catalysis Letters, 111, p. 43 (2006)

A. Sakthivel. A. K. Hijazi, M. Hanzlik, A. S.T. Chiang, F. E. Kühn, 2005, Heterogenization of Cu(NCCH3)6][B(C6F5)4]2 and its Application in Catalytic Olefin Aziridination, Applied Catalysis A: General, 294, p. 161

Syukri, A. K. Hijazi, A. Sakthivel, A. I. Al-Hmaideen and F. E. Kühn, Heterogenization of Solvent-Ligated Copper(II) Complexes on Poly(4-Vinylpyridine) for the Catalytic Cyclopropanation of Olefins, Inorganica Chimica Acta, 360, p. 197 (2007)

Bergna, Horacio E., William O. Roberts, Colloidal Silica: Fundamentals and Applications, Surfactant Science Series, Vol. 131, CRC Press (2006)

Herguth, William R., Applications of Scanning Electron Microscopy and Energy Dispersive Spectroscopy (SEM/EDS) to Practical Tribology Problems, Herguth Laboratories, Inc

Barbara Stuart, Infrared Spectroscopy: Fundamentals and Applications, John Wiley & Sons, Ltd (2004).

Downloads

Published

2015-02-11

How to Cite

-, S. (2015). GRAFTING TEMBAGA(II) PADA SILIKA MODIFIKASI. Jurnal Riset Kimia, 4(2), 1. https://doi.org/10.25077/jrk.v4i2.116

Issue

Vol. 4 No. 2 (2011): March

Section

Articles

Citation Check

License

Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.

1. License

The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License. 

2. Author(s)' Warranties

The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).

3. User Rights

Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.

4. Rights of Authors

Authors retain all their rights to the published works, such as (but not limited to) the following rights;

  • Copyright and other proprietary rights relating to the article, such as patent rights,
  • The right to use the substance of the article in own future works, including lectures and books,
  • The right to reproduce the article for own purposes,
  • The right to self-archive the article,
  • The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.

5. Co-Authorship

If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.