PERUBAHAN KOMPOSISI METIL ESTER AKIBAT KERUSAKAN PANAS PADA METIL ESTER SULFONAT DARI JARAK PAGAR

Authors

  • Sri Hidayati

DOI:

https://doi.org/10.25077/jrk.v5i1.183

Abstract

Vol 5 No 1

ABSTRACT

 

Surfactant is a surface-active agent that can be produced by a chemical or biochemical synthesis. The most widely used anionic surfactant in surfactant flooding is linier alkyl benzene sulfonate (LAS) synthesized from petroleum material. The weaknesses of petroleum based surfactant are: it is made from nonrenewable resources, has very poor detergency in hard water and naturally are difficult to be degraded. These problems can be overcome by producing methyl ester sulfonate (MES) surfactant made from natural resources, such jatropha oil es methyl ester. Temperature is the important factor that should be performed in MES stability. The purpose of this research is to investigate the sulfonate group caused by temperature and degradation time. The result of thermal degradation tests of Methyl Ester Sulfonates showed that at temperature of 150 oC during 72 hours influenced the degradation of sulfonate group. It was indicated by decreasing peak of sulfonate formed at the wave number of 1250 – 1150 cm-1. The increased of temperature showed decreased ability of surfactant to stabilized of emulsion and surface tension.

 

Keywords: methyl ester sulfonates, thermal degradation

References

Unisource Canada, GLOSSARY. Unisource Canada, Inc, 2005. http://www.unisour-ce.ca/upload/tools/facility_supply_glossary_en_g.pdf, 30/11/2006

L. L. Schramm, E. N. Stasiuk, H. Yarranton, B. B. Maini, and B. Shelfantook, Tempe-rature effects in the conditioning and flotation of bitumen from oil sands in terms of oil recovery and physical properties, Petroleum Society-Canadian Institute of Mining, Metallurgy & Petroleum, Paper., 2002-074, www.ucalgary.ca/~schr- amm/CIPC_2002_074.pdf 15/03/2006

V. A. Hackley and C. F. Ferraris, The use of nomenclature in dispersion science and technology, national institute of standards and technology: special publication 960-3, U.S, Government Printing Office, Washington, 2001, www.nist.gov/public_ affairs/practiceguidesember/SP960-3.pdf,17/03/2006

J. L. Salager, Surfactants types and uses, version 2. FIRP Booklet # E300-A: Teaching Aid in Surfactant Science & Engineering in English, Universidad De Los Andes, Mérida-Venezuela, 2002, http: //www.firp.ula.ve/cuadernos/E300A pdf, 20/03/2005

Particle Engineering Research Center, Surfactants, Univ. of Florida, www.unmc. edu/pharmacy/wwwcourse/p_surfactants_00_files/p_surfactants.ppt, 20/11/2005

W. H. D. Groot, Sulphonation technology in the detergent house, Kluwer Academic Publisher, Netherland, 1991.

Y.H. Hui, Bailey’s Industrial Oil and Fat Products, 5th Edition Vol. 5, John Willey & Sons, Inc, New York.7, 1996.

K. L. Matheson, Formulation of household and industrial detergent, in: soap and detergent: a theoretical and practical review, Splitz, L (ed). AOCS Press,Champaign, Illinois, 1996.

P. C. Hui and M. E Tuvell, a Mechanistic approach to the thermal degradation of α olefin sulfonates, JAOCS., 65(6), 1988.

P. Zhao, Development of high performance surfactant for difficult oil, Thesis The University of Texas at Austin, 122, (2007).

V. M. Zigler and L. L. Handy, Effect of temperature on surfactant adsorbsiin porous media, Journal Soc, Pet, Eng., 218-228, (1981).

S. Hidayati, Perancangan proses produksi metil ester sulfonat dari minyak sawit inti sawit dan uji efektivitasnya untuk pendesakan minyak bumi, 2006.

American Society for Testing and Material (ASTM), Annual Book of ASTM Standards: Soap and Other Detergents, Polishes, Leather, Resilient Floor Covering, Baltimore: ASTM, 2001.

AOAC, Official Method of Analysis of the Association of Official Analytical Chemist, AOAC, Washington, 1995.

M. H. S. Ginting dan N. Herlina, Tegangan Permukaan cairan dengan metode drop out dan metode buble. USY Digital Library, 2002.

Foster et all, Sulfonation and sulfation process. The Chemithon Corporation.

R. A. Williams and S. J. R Simon, Handling colloidal material in colloid and surface engineering application in process industries, Oxford: Bitterworth-Heinemann Ltd, 1992.

K. Sutriah, T. T. Irawadi, M. Farid, M. Khotib, B. M. Soebrata, dan H. Purwaningsih, Sintesis dan pencirian surfaktan berbasis minyak sawit dan karbohidrat untuk aditif produk pangan dan detergen, Prosiding Seminar Nasional Himpunan Kimia Indonesia, IPB Bogor, 259-270, (2006).

R. L. Peesok, Shields, T. Coumrns, and M. William, Modern Method of Chemical Analysis, Edisi ke-2, New York: John Willey & Sons, Inc, 1976.

R. M. Silverstein and F. X Webster, Spectrometric Identification Organic Com-pound, John Willey & Sons, Inc, New York, 1988.

F. A. Russin, F. R V. Voor and J. Sedman, Novel method to rapid monitoring of lipid oxidation by FTIR spectroscopy using disposable IR Card. JAOCS, 80(7): 202-208, (2003).

J. Samuelsson and M. Johansson, Oxidation of FA with alkana or alkyl functionalities studied with chemiluminescence and real time IR Spectroscopy, JAOCS, 80(5): 491-496, (2003).

R. Edison dan S. Hidayati, Production surfactant methyl ester sulfonate (MES) of jatropha oil (Jatropha Curcas L.) with temperature and time sulfonation, temperature purification, and concentration methanol settings, Proceeding International Seminar on Sustainable Biomass Production and Utilization Challenges and Oppor-tunities (ISOMASS) August, 3-4, 2009.

F. Riyanti, P. Loekitowati, dan R. Muharran, Pengaruh pemanasan dan penambahan antioksidan bht pada minyak biji ketapang dan kinetika reaksi oksidasi, Seminar Nasional Sains IV, 2011.

R. Aminah, Pengaruh pemanasan pada minyak goreng yang diobservasi pada tikus putih. pusat penelitian penyakit tidak menular, Badan Penelitian dan Pengem-bangan Kesehatan Dep. Kes. RI, Jakarta, 2002.

R. A. D. Sartika, Pengaruh suhu dan lama proses menggoreng (deep friyng) terhadap pembentukan asam lemak trans. Makara Sains., 13(1): 23-28, 2009.

S, K. L. D. Parkin and O. R. Fennema, Fennema’s Food Chemistry. Fourt Edition. CRC Press, New York, 2007.

W. W. Cristie, Triacylglycerols-structure, composition and analysis. The lipid Library, 2004.

Downloads

Published

2015-02-12

How to Cite

Hidayati, S. (2015). PERUBAHAN KOMPOSISI METIL ESTER AKIBAT KERUSAKAN PANAS PADA METIL ESTER SULFONAT DARI JARAK PAGAR. Jurnal Riset Kimia, 5(1), 60. https://doi.org/10.25077/jrk.v5i1.183

Issue

Vol. 5 No. 1 (2011): September

Section

Articles

Citation Check

License

Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.

1. License

The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License. 

2. Author(s)' Warranties

The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).

3. User Rights

Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.

4. Rights of Authors

Authors retain all their rights to the published works, such as (but not limited to) the following rights;

  • Copyright and other proprietary rights relating to the article, such as patent rights,
  • The right to use the substance of the article in own future works, including lectures and books,
  • The right to reproduce the article for own purposes,
  • The right to self-archive the article,
  • The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.

5. Co-Authorship

If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.