PENYERAPAN ION LOGAM Cr(III) DAN Cr(VI) DALAM LARUTAN MENGGUNAKAN KULIT BUAH JENGKOL (Pithecellobium jiringa (JACK) PRAIN.)

Authors

  • Zulkarnain Chaidir Laboratorium Biokimia Jurusan Kimia FMIPA, Universitas Andalas, Indonesia
  • Qomariah Hasanah Laboratorium Kimia Lingkungan Jurusan Kimia FMIPA, Universitas Andalas
  • Qomariah Hasanah Laboratorium Kimia Lingkungan Jurusan Kimia FMIPA, Universitas Andalas
  • Rahmiana Zein Laboratorium Kimia Lingkungan Jurusan Kimia FMIPA, Universitas Andalas
  • Rahmiana Zein Laboratorium Kimia Lingkungan Jurusan Kimia FMIPA, Universitas Andalas

DOI:

https://doi.org/10.25077/jrk.v8i2.239

Keywords:

Jengkol shells, metal ions Cr VI, metal ions Cr III, biosorption, isotherms

Abstract

Jengkol shells (Pithecellobium jiringa) an agricultural waste from typical Indonesian plant has been investigated for its ability to absorb heavy metal ions Cr VI and Cr III . Effect of pH, concentration, contact time, mass and the speed of stirring biosorben studied by extraction method. Concentration of metal ions Cr VI and Cr III was measured using Atomic Absorption Spectrophotometer (AAS). The optimum conditions for metal ion uptake of Cr VI occurs at pH 4, the concentration of 7000 mg/L, contact time of 60 minutes, 0.1 g biosorben mass and stirring speed 100 rpm. For the metal ions Cr III wa obtained conditions optimum at pH 5, the concentration of 1500 mg/L,  contact time of 60 minutes, 0.1 g biosorben mass and stirring speed 100 rpm. Functional groups contained in the jengkol shells analyzed by Fourier Transform Infra Red (FTIR). Data equilibrium uptake of metal ions Cr VI and Cr III  by the jengkol shells analyzed using two isotherm models , namely Langmuir and Freundlich isotherm models . The absorption of both the metal ions tend to follow the Langmuir isotherm models in which the absorption capacity of metal ions obtained for Cr VI ) and Cr  III  is 24.9376 mg / g and 39. 0625 mg /g . The optimum condition was applied to study the river Batang Arau at Padang city obtained a capacity of 15.065 mg/ g with 45 efficiency, 94 % for the uptake of metal ions Cr (total).

References

Stift, Anton., Succesful Treatmen of a Patient Suffering from Severe Acute Pottasium Dichromate Poisoning With Liver Transplatation. Journal Departement of General and Trasplantation Surgery University of Vienna, Vienna, Austria. 2000.

Kamran Anjana, and Anubha Kaushik, Bala Kiran. Biosorption of Cr(VI) by immobilized biomass of two indigenous strains of cyanobacteria isolated from metal contaminated soil. J. of Hazardous Materials. 148 (2007) 383–386.

Diantariani, N.P., Sudiarta, I.W., and Elantiani, N.K. Proses Biosorpsi dan Desorpsi Ion Cr(VI) pada Biosorben Rumput Laut Eucheuma spinosum. J. Kimia Jurusan Kimia FMIPA Universitas Udayana, 2 (2008) 45-52.

Ulfin, Ita, and Widya W. Studi Penyerapan Kromium Dengan Kayu Apu (Pistia,L). Akta Kimindo Jurusan Kimia Institut Teknologi Sepuluh November, No 1 Vol 1(2005) 41-48.

Munaf, Edison., Zein, R.,Refilda., Deswita and Besti, Yuliza., Penyerapan Ion Kromium dalam Air Limbah Oleh biosorben Kulit Kacang dengan Deteksi Spektroskopi Serapan Atom. J. Kimia Andalas. 5 (1999).

Zein, R.,Suhaili, R.,Earnestly, Indrawati, dan Munaf, E. Removal of Pb(II), Cd(II), and Co(II) from aqueous solution using Garcinia mangostana L fruit shell. Hazardous Material.181 (2010) 52-56.

Donmez, Gonul., Aksu, Zumriye. Removal of Chromium Cr(VI) From saline Waterwaters by Dunaliella Species. J. Process Biochemistry 38 (2001) 751-762.

Munaf, E., Haryati, Sri.,Suyani Hamzar., Dharma, Abdhi. Penyerapan Ion Kromium (III) dan Kromium (VI) dalam Air Menggunakan Tepung Eceng Gondok dan Study Regenerasinya. J. Kimia Andalas, 6 (2000) 65-71.

Munaf E., Zein R., Refilda dan Maryati Y. Pemanfaatan sabut kelapa sawit untuk menyerap ion logam cadmium dan kromium dalam air limbah. J. Kimia Andalas, 5 (1999) 10-14.

Stefii. Lampiran Hasil Identifikasi Tumbuhan Jengkol (PitheCellobium Lobatum Benth). Laboratorium Taksonomi Tumbuhan Departemen Biologi FMIPA Universitas Sumatera Utara. 2010

Susanti, Eni. Pemanfaatan Kulit Jengkol (Pithecellobium jiringa) sebagai Biohrbisida dan Biolarvasida Aedes aegepty. Karya Tulis Mahasiswa Berprestasi Universitas Negeri Medan, Sumatera Utara. 2010

Patimah, S., Abun, and Supratman, R.H. Pengaruh Penambahan Ekstrak Kulit Jengkol (Pithecellobiumjiringa (Jack) Prain) dalam Ransum Terhadap Jumlah koloni Bakteri Escherichia coli dan Lactobacillus sp. Pada usus Halus Ayam Broiler. Thesis Fakultas Peternakan Universitas Padjadjaran. 2012

Adrian, Nur. Alat Analisa. Materi Ajar Jurusan Teknik Kimia Fakultas Teknik Universitas Sebelas Maret. 2009.

Wang, J., dan Chen, C. Biosorption of Heavy Metals By Saccharomyses Cerevisiae: J A Review. Biotechnology Adv. vol.24 (2006) 427-451.

Gupta,V.K., dan Rastogi, A. Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solution. J. of Hazardaous Materia, 163 (2009) 396-402.

Guti´errez N., Ramo E., and Contreras, A. Removal of chromium (VI) from aqueous solutions by hydrotalcite-like compounds: kinetic and equilibrium studies. Revista Mexicana De F´Isicas, 55 (2009) 135–138.

Abhillash, Mehta.K.D., Kumar.V., and Perdey, B.D. Biosorption of Trivalent chromium from a Model Tanning Solution by Adapted Aspergillus niger. M.E.F Division, National Metallurgical Laboratory. 2007

Ramadhan, B., Handajani, M. Biosorpsi logam berat Cr VI dengan menggunakan biomassa Saccharomyces cerevisiae. Makalah Seminar, Program Studi Tehnik Lingkungan Fakultas Tehnik Sipil dan Lingkungan ITB. 2007

Deng, Shubo dan Ting, Peng Yen. Polyethylenimine-Modified Fungal Biomass as a High-Capacity Biosorbent for Cr(VI) Anions; sorption Capacity and Uptake Mechanism. Environ.Sci.Techol , 39 (2005) 8490-8496.

Raju,D.S.S.R., Kiran, G.A.R., dan Rao,Dr.V.N. Comparison studies on biosorbtion of lead (II) from an aqueous solution using Anacardium occidentale and Carica papaya leaves powder. J. Emerging Trends In Engineering and Development, vol.3 (2013) 273-283.

Putri, Lenni Erika. Penyerapan Ion Logam Cr VI Menggunakan Serbuk Kulit Manggis (Garcinia mangostana L) yang telah ditarik Zat Warnanya, Jurnal Skripsi Kimia FMIPA Universitas Andalas. 2007

Munagapati, V.S., Yarramuthi,V., Nadavala, S.K. Alla, S.R., and Abburi,K. Biosorption of Cu(II), Cd (II) and Pb (II) by Acacia leucocephala bark powder : Kinetics, equilibrium and Thermodynamics. Chem. Eng.J., Vol. 157 (2010) 357-365.

Saueprasearsit, P., Nuanjaraen, M., and Chinpala, M. Biosorption of Lead (Pb2+) by Luffa cylindrical Fiber. Environ. Res. J, vol.4 (2010) 157-166.

Chuah, T. G., Jumasiah, A., Azni,l., Katayon, S., and Choong, S. Y. Rice husk potentially low-cost biosorbent for heavy metal and dye removal: an overview. Desalination , Vol. 175 (2005) 305-316.

Chhikara, S., Hooda, A., Rana, L., dan Dhankhar, R. Chromium (VI) biosorption by immobilized Aspergillus niger in continuous flow system with special reference to FTIR analysis. J. of Environmetal Biologi, 31 (2010) 561-566.

Witek-Krowiak, Anna. , Szafran, Roman G., and Modelski,Szymon. Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent. Desalination. 265 (2011) 126-134

Ata, Ayca. , Nalcaci, Orkun Ovez., Ovez, Bikem. Macro algae Gracilaria verrucosa as a biosorbent: A study of sorption mechanisms. Algal Research xxx. 2012.

Ucun, Handan., Kemal, Bayhan Y., Yusuf, Kaya., Avni, Cakici dan Faruk, Algur O. Biosorption of chromium (VI) from aqueous solution by cone biomass of Pinus sylvestris. Bioresource Technology. 85 (2002) 155-158.

Cetinkaya, Donmez G., Aksu, Z., Oztruk, A., and Kutsal, T., A. Comparative study on heavy metal biosorption characteristics of some algae. Process Biochemistry. 34 (1999) 885-892.

Bai, Sudha R., and Abrham, Emilia. Studies on chromium (VI) adsorption-desorption using immobilized fungal biomass. Bioresource Technology. 87 (2003) 17-26.

Prakasham, R. S., Merrie, J.S., Sheela, R., Saraswati, N., and Ramakrishnan, S.V. Biosorption of Chromium (VI) by free and immobilized Rhizopus arrhizus. Environmental Pollution. 104 (1999) 421-427.

Gautam K., Nagda dan Vikram S., and Ghole. Glutaraldehyde Treated Tendu Waste from Bidi Industry as an Efficient Sorbent for Chromium from Aqueous Solution. Global Journal of environmental Research. 3(2009) 274-279.

Gupta, V.J., and Rastogi A. Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solutions. J. of Hazardous Materials. 163 (2009) 396–402.

Krishna R., and Padma Sree R. Removal of Chromium from Aqueous Solution by Custard Apple (Annona Squamosa) Peel Powder as Adsorbent. International Journal of Applied Science and Engineering. 11 (2013) 171-194.

Ahalya, N. Biosorption of chromium (VI) from aqueous solutions by the husk of Bengal gram (Cicer arientinum). Electronic Journal of Biotechnology ISSN: 0717-3458. 8 (2005).

Abirami, S., Srisudha, S., and Gunasekaran, P. Biosorpsi of Chromium from Tanner Effluent Using Biomass of Sargassum Wightii (Greville). Int Pharm Bio Sci. 3 (2012) 584-595.

Selvi, K., Pattabhi,S., and Kadirvelu,K. Removal of Cr(VI) From Aqueous Solution by Adsorption onto activated Carbon. J. Bioresource Thecnology. 80 (2001) 87-89.

Oktay, H., Maharramov, Abel M., Akprov, and Elchin O. Modified Maleic anhydride- allypropionate- styrene terpolymer as Adsorbent for Removal Copper Ions From Aqueous Solution. J. Int.Chem. environ. 2 (2012) 220-227.

Onwuka J. C.I., Ajibola V. O., Kagbu J. A., and Manji A. Biosorption of Cr(VI) and Co(II) ions from Synthetic Wastewater using Dead Biomass of Fresh Water Green Algae Cosmarium panamense, Archives of Applied Science Research. 3 (2011) 191-207.

M.A,Dabhade., Saidutta,M.B., and Murthy, D. Adsorption of Phenol on Granular Activated Carbon from Nutrient Medium:Equilibrium and kinetic Study Int. J. Environ. Res. 3 (2009) 557-568.

Mishra, Vishal., Balomajumder, Chandrajit., Agarwal, Vijay, and Kumar. Biosorption of Zn (II) Ion Onto Surface of Cedrus Deodara sawdust: Studies on Isoterm Modeling and Surface Characterization. International J. of Chemical Sciences and Applications. 2 (2011) 179-185.

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Published

2015-04-01

How to Cite

Chaidir, Z., Hasanah, Q., Hasanah, Q., Zein, R., & Zein, R. (2015). PENYERAPAN ION LOGAM Cr(III) DAN Cr(VI) DALAM LARUTAN MENGGUNAKAN KULIT BUAH JENGKOL (Pithecellobium jiringa (JACK) PRAIN.). Jurnal Riset Kimia, 8(2), 189. https://doi.org/10.25077/jrk.v8i2.239

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Vol. 8 No. 2 (2015): March

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