Pemanfaatan Cangkang Telur dan Sekam Padi Sebagai Bioadsorben Metilen Biru pada Limbah Tekstil
DOI:
https://doi.org/10.25077/jrk.v12i1.396Keywords:
Adsorption, Synthetic dyes, Rice husks, Eggshells, BioadsorbentAbstract
The textile industry in Indonesia has increased since the 1980s. From the non-oil and gas sector, the textile industry is the government's largest source of income. In addition to its impressive growth, about 10-15% of the used textile dyestuff is wasted at the dyeing process can exceed the maximum Chemical Oxygen Demand level of 150 mg/L. Synthetic dyes contain carcinogenic ingredients that can harm the environment and aquatic biota. The alternative for handling the dye waste is the adsorption method using bio adsorbent from a mixture of chicken eggshells and rice husk ash. Both have the potential to be used as adsorbents because they have an active site, abundant amounts, and are economical. This study was to determine the effect of the process variables of the adsorbent mass ratio, contact time, and pH on the adsorption capacity of methylene blue using a mixture of eggshells and rice husk ash with the UV-Vis Spectrophotometer analysis method. The results showed that the optimal conditions for the adsorption of 20 ppm methylene blue were 0.2:0.8 gram of adsorbent ratio, 80 minutes, and pH of 3. The adsorption capacity obtained was 98.817%, reduced the methylene blue concentration to 0.237 ppm.Â
References
Atmaji, P., Purwanto, W., Pramono, E. P., Daur ulang limbah hasil pewarnaan industri tekstil. J. Sains dan Teknol. Indones., 1(4): 9–15 (1999).
Selvam, K., Swaminathan, K. & Chae, K. S., Decolourization of azo dyes and a dye industry effluent by a white rot fungus Thelephora sp. Bioresour. Technol., 88(2): 115–119 (2003).
Huda, T. & Yulitaningtyas, T. K., Kajian Adsorpsi Methylene Blue Menggunakan Selulosa dari Alang-Alang. Indones. J. Chem. Anal., 1(1): 9–19 (2018).
Zille, A., Laccase Reactions for Textile Applications Andrea Zille Laccase Reactions for Textile Applications. Universidade do Minho, (2005).
Laksono, E. W., Kajian penggunaan adsorben sebagai alternatif pengolahan limbah zat pewarna tekstil. in Prosiding Seminar Nasional FMIPA UNY, (2009).
Haryono, H., Faizal D, M., Liamita N, C. & Rostika, A., Pengolahan Limbah Zat Warna Tekstil Terdispersi dengan Metode Elektroflotasi. EduChemia (Jurnal Kim. dan Pendidikan), 3(1): 94 (2018).
Zulfikar, M. A., Mariske, E. D. & Djajanti, S. D., Adsorption of lignosulfonate compounds using powdered eggshell. Songklanakarin J. Sci. Technol., 34(3): 309–316 (2012).
Ehrampoush, M. H. & Ghaneian, M. T., Equilibrium and Kinetics Study of Reactive Red 123 Dye Removal From Aqueous Solution By Adsorption on. Iranian J. Environ. Health Sci. Eng., 8(2): 101–108 (2011).
Tammi, T., Suaniti, N. & Manurung, M., Variasi Konsentrasi Dan Ph Terhadap Kemampuan Kitosan Dalam Mengadsorpsi Metilen Biru. J. Kim., 7(1): 11–18 (2013).
Erawati, E. & Helmy, E., pembuatan karbon aktif dari gergaji kayu jati (Tectona grandis L,f) (ukuran partikel dan jenis aktivator). Proceeding of The URECOL, 97–104 (2018).
Hajar, E. W. I., Sitorus, R. S., Mulianingtias, N. & Welan, F. J., Efektivitas Adsorpsi Logam Pb2+ Dan Cd2+ Menggunakan Media Adsorben Cangkang Telur Ayam. Konversi, 5(1): 1–7 (2016).
Prima Astuti Handayani., Nurjanah, E. & Rengga, W. D. P., Pemanfaatan Limbah Sekam Padi Menjadi Silika Gel Prima. 4(2): 55–59 (2015).
Wijayanti, I. E. & Kurniawati, E. A., Studi Kinetika Adsorpsi Isoterm Persamaan Langmuir dan Freundlich pada Abu Gosok sebagai Adsorben. EduChemia (Jurnal Kim. dan Pendidikan), 4(2): 175 (2019).
Wardalia., Karakterisasi Pembuatan Adsorben Dari Sekam Padi Sebagai Pengadsorp Logam Timbal Pada Limbah Cair. J. Integr. Proses, 6(2): 83–88 (2016).
Haqiqi, E. R., Prosiding SEMNAS Kimia Unpad. Analisis FTIR (Fourier Transform InfraRed) Adsorben Zat Warna dari Limbah Cangkang Telur Ayam Dikombinasi Biomassa Sekam Padi, 17–25 (2018).
Pardede, E., Pemurnian Minyak Jelantah Menggunakan Adsorben Berbasis Cangkang Telur. J. Atmos., 1(1): 8–16 (2020).
Misfadhila, S., Azizah, Z., Rusdi. & Chaniago, cynthia diane P., Pengaplikasian Cangkang Telur Dan Karbon Aktif Sebagai Adsorben Logam Timbal. Farm. Higea, 10(2): 1–8 (2018).
Padi, D. S., Sintesis Dan Karakterisasi Natrium Silikat ( Na2SiO3 ). 7: 90–97 (2015).
Nurlaili, T., Kurniasari, L. & Ratnani, R. D., Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Adsorben Zat Warna Methyl Orange Dalam Larutan. J. Inov. Tek. Kim., 2(2): (2017).
Kristiyani, D., Susatyo, E. B. & Prasetya, A. T., Pemanfaatan zeolit abu sekam padi untuk menurunkan kadar ion Pb2+ pada air sumur. Indones. J. Chem. Sci., 1(1): (2012).
Riapanitra, A., Setyaningtyas, T. & Riyani, K., Penentuan waktu kontak dan pH optimum penyerapan metilen biru menggunakan abu sekam padi. Molekul, 1(1): 41 (2006).
Hadayani, L., Riwayati, I. & Ratnani, R., Adsorpsi Pewarna Metilen Biru Menggunakan Senyawa Xanthat Pulpa Kopi. J. Momentum UNWAHAS, 11(1): 114174 (2015).
Downloads
Published
How to Cite
Issue
Section
Citation Check
License
Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.
1. License
The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License.Â
2. Author(s)' Warranties
The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).
3. User Rights
Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.
4. Rights of Authors
Authors retain all their rights to the published works, such as (but not limited to) the following rights;
- Copyright and other proprietary rights relating to the article, such as patent rights,
- The right to use the substance of the article in own future works, including lectures and books,
- The right to reproduce the article for own purposes,
- The right to self-archive the article,
- The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
5. Co-Authorship
If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.