Pengolahan Limbah Pewarna Metilen Biru Menggunakan Arang Aktif dan Zeolit Aktif dengan Katalis Fe dan Oksidator Hidrogen Peroksida


  • Maryudi Maryudi Program Studi Teknik Kimia, Fakultas Teknologi Industri, Universitas Ahmad Dahlan, DI Yogyakarta, Indonesia
  • Agus Aktawan Program Studi Teknik Kimia, Fakultas Teknologi Industri, Universitas Ahmad Dahlan, DI Yogyakarta, Indonesia
  • Shinta Amelia Program Studi Teknik Kimia, Fakultas Teknologi Industri, Universitas Ahmad Dahlan, DI Yogyakarta, Indonesia



adsorption, activated charcoal, activated zeolite, Fe, hydrogen peroxide


The textile industry including batik has provided broad benefits to society from an economic standpoint. However, there is negative impact from wastewater generated in the production process, which is containing dyes. Various types of dyes are used in the coloring process, and methylene blue is one of most used dye. Various ways have been done to treat wastewater containing methylene blue. Methylene blue processing techniques by adsorption have been carried out with various types of adsorbents. Research on the comparison of the ability of commercial activated charcoal and commercial activated zeolite to adsorb methylene blue was carried out with the addition of an Fe catalyst and a hydrogen peroxide oxidizer. The results showed that the addition of Fe catalyst would increase the degradation of methylene blue in the waste either with activated charcoal or activated zeolite. The combination of using Fe catalyst and hydrogen peroxide oxidizer further increases the removal of methylene blue in both types of adsorbents, activated charcoal and activated zeolite. Activated zeolite has the better ability to adsorb methylene blue than activated charcoal under various conditions.


Mozammel, H. M., Masahiro, O. & Bhattacharya, S. C., Activated charcoal from coconut shell using ZnCl2 activation. Biomass and Bioenergy, 22(5): 397–400 (2002).

Mukimin, A., Zen, N., Purwanto, A., Wicaksono, K. A., Vistanty, H. & Alfauzi, A. S., Application of a full-scale electrocatalytic reactor as real batik printing wastewater treatment by indirect oxidation process. J. Environ. Chem. Eng., 5(5): 5222–5232 (2017).

Rashidi, H. R., Sulaiman, N. M. N. & Hashim, N. A., Batik industry synthetic wastewater treatment using nanofiltration membrane. Procedia Eng., 44: 2010–2012 (2012).

Hameed, B. H. & Ahmad, A. A., Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. J. Hazard. Mater., 164(2–3): 870–875 (2009).

Hamdaoui, O. & Chiha, M., Removal of methylene blue from aqueous solutions by wheat bran. Acta Chim. Slov., 54(2): 407–418 (2007).

Kumar, P. S., Ramalingam, S. & Sathishkumar, K., Removal of methylene blue dye from aqueous solution by activated carbon prepared from cashew nut shell as a new low-cost adsorbent. Korean J. Chem. Eng., 28(1): 149–155 (2011).

Gürses, A., Karaca, S., Doǧar, Ç., Bayrak, R., Açikyildiz, M. & Yalçin, M., Determination of adsorptive properties of clay/water system: methylene blue sorption. J. Colloid Interface Sci., 269(2): 310–314 (2004).

Chowdhury, S., Mishra, R., Saha, P. & Kushwaha, P., Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk. Desalination, 265(1–3): 159–168 (2011).

Saha, P., Chowdhury, S., Gupta, S. & Kumar, I., Insight into adsorption equilibrium, kinetics and thermodynamics of malachite green onto clayey soil of Indian origin. Chem. Eng. J., 165(3): 874–882 (2010).

Malato, S., Blanco, J., Cáceres, J., Fernández-Alba, A. R., Agüera, A. & Rodríguez, A., Photocatalytic treatment of water-soluble pesticides by photo-Fenton and TiO2 using solar energy. Catal. Today, 76(2–4): 209–220 (2002).

Wu, Q., Zhao, J., Qin, G., Wang, C., Tong, X. & Xue, S., Photocatalytic reduction of Cr(VI) with TiO2 film under visible light. Appl. Catal. B Environ., 142: 142–148 (2013).

Babu, D. S., Srivastava, V., Nidheesh, P. V. & Kumar, M. S., Detoxification of water and wastewater by advanced oxidation processes. Sci. Total Environ., 696: 133961 (2019).

Arzate, S., Pfister, S., Oberschelp, C. & Sánchez-Pérez, J. A., Environmental impacts of an advanced oxidation process as tertiary treatment in a wastewater treatment plant. Sci. Total Environ., 694: 133572 (2019).

Poblete, R., Cortes, E., Bakit, J. & Luna-Galiano, Y., Landfill leachate treatment using combined fish scales based activated carbon and solar advanced oxidation processes. Process Saf. Environ. Prot., 123: 253–262 (2019).

Cao, Y., Wang, K., Wang, X., Gu, Z., Ambrico, T., Gibbons, W., Fan, Q., et al., Preparation of active carbons from corn stalk for butanol vapor adsorption. J. Energy Chem., 26(1): 35–41 (2017).

Chmielewská, E., Natural zeolite: Alternative adsorbent in purification or post-treatment of waters. in Modified Clay and Zeolite Nanocomposite Materials, (eds. Mercurio, M., Sarkar, B. & Langella, A.), Elsevier, 87–112 (2019).

Moideen, S. N. F., Din, M. F. M., Rezania, S., Ponraj, M., Rahman, A. A., Pei, L. W., Ismail, Z., et al., Dual phase role of composite adsorbents made from cockleshell and natural zeolite in treating river water. J. King Saud Univ. - Sci., 32(1): 1–6 (2020).

Wang, S. & Peng, Y., Natural zeolites as effective adsorbents in water and wastewater treatment. Chem. Eng. J., 156(1): 11–24 (2010).

Hor, K. Y., Chee, J. M. C., Chong, M. N., Jin, B., Saint, C., Poh, P. E. & Aryal, R., Evaluation of physicochemical methods in enhancing the adsorption performance of natural zeolite as low-cost adsorbent of methylene blue dye from wastewater. J. Clean. Prod., 118: 197–209 (2016).

Glaze, W. H., Kang, J. W. & Chapin, D. H., The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation. Ozone Sci. Eng., 9(4): 335–352 (1987).

Rueda-Márquez, J. J., Pintado-Herrera, M. G., Martín-Díaz, M. L., Acevedo-Merino, A. & Manzano, M. A., Combined AOPs for potential wastewater reuse or safe discharge based on multi-barrier treatment (microfiltration-H2O2/UV-catalytic wet peroxide oxidation). Chem. Eng. J., 270: 80–90 (2015).

Zhou, J., Liu, P., Liu, Z., Zhang, J. & Huang, X., Simultaneous recovery of phosphorus with nickel purification in nickel-plating wastewater via Fe/C activated H2O2 oxidation. Chem. Eng. J., 381: 122702 (2020).

Muruganandham, M. & Swaminathan, M., Advanced oxidative decolourisation of Reactive Yellow 14 azo dye by UV/TiO2, UV/H2O2, UV/H2O2/Fe2+ processes-a comparative study. Sep. Purif. Technol., 48(3): 297–303 (2006).

Hassaan, M. A., El Nemr, A., El-Zahhar, A. A., Idris, A. M., Alghamdi, M. M., Sahlabji, T. & Said, T. O., Degradation mechanism of Direct Red 23 dye by advanced oxidation processes: a comparative study. Toxin Rev., 1–10 (2020).

Hassaan, M. A., El Nemr, A. & Madkour, F. F., Testing the advanced oxidation processes on the degradation of Direct Blue 86 dye in wastewater. Egypt. J. Aquat. Res., 43(1): 11–19 (2017).

Ilomuanya, M. O., Nashiru, B., Ifudu, N. D. & Igwilo, C. I., Effect of pore size and morphology of activated charcoal prepared from midribs of Elaeis guineensis on adsorption of poisons using metronidazole and Escherichia coli O157:H7 as a case study. J. Microsc. Ultrastruct., 5(1): 32–38 (2017).

Bansal, R. C. & Goyal, M., Activated carbon adsorption. CRC Press, (2005).

Amelia, S., Rahmadani, W., Amalia, L. R. & Mufrodi, Z., Degradation of surfactant waste of leather tanning using Fe2O3/activated carbon catalyst. Maj. Kulit, Karet, dan Plast., 35(2): 49–54 (2020).

Amelia, S., Sediawan, W. B., Mufrodi, Z. & Ariyanto, T., Modification of iron oxide catalysts supported on the biomass based activated carbon for degradation of dye wastewater. J. Bahan Alam Terbarukan, 7(2): 164–168 (2019).




How to Cite

Maryudi, M., Aktawan, A., & Amelia, S. (2021). Pengolahan Limbah Pewarna Metilen Biru Menggunakan Arang Aktif dan Zeolit Aktif dengan Katalis Fe dan Oksidator Hidrogen Peroksida. Jurnal Riset Kimia, 12(2).




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