Decreasing of Mangan (II) in The Water Using Membrane of Moringa Seed Powder-TiO2 with Variation of Mass TiO2

Authors

  • Ana Hidayati Mukaromah Department Magister of Clinical Laboratory Science, Universitas Muhammadiyah Semarang, Indonesia https://orcid.org/0000-0001-8492-4961
  • Fandhi Adi Wardoyo Department of Health Analyst, Faculty of Nursing and Health, Universitas Muhammadiyah Semarang, Indonesia
  • Ayu Rahmawati Sulistyaningtyas Department of Health Analyst, Faculty of Nursing and Health, Universitas Muhammadiyah Semarang, Indonesia
  • Haikal Naufal Ghazi Department of Health Analyst, Faculty of Nursing and Health, Universitas Muhammadiyah Semarang, Indonesia

DOI:

https://doi.org/10.25077/jrk.v14i1.512

Keywords:

Moringa Seeds Powder (MSP), TiO2, Mangan (II), membrane MSP-TiO2

Abstract

Mn (II) is a metal ion commonly used in steel alloys, pigment industries, welding, fertilizers, pesticides, ceramics, and electronics. According to the Regulation of the Minister of Health No. 32 of 2017, the permissible content of Manganese in dug well water is 0.5 mg/L. The purpose of this study was to determine the concentration of Mn (II) ions in water before and after passing through a Moringa Seeds Powder (MSP)-TiO2 membrane 20:1; 20:3; 20:5; 20:7; 20:9 and measure the percentage decrease in the concentration of Mn (II) ions in water after through the MSP-TiO2 membrane. The object of this research is a 55 ppm Mn (II) ion artificial sample at a flow rate of 0.56 mL/minute for 90 minutes with 90-watt radiation UV. The concentration of Mn (II) ion was measured by visible spectrophotometric method, the morphology of MSP, TiO2, and MSP-TiO2 membranes was characterized by SEM-EDX, and its diffraction spectra by X-Ray diffraction. The results obtained that the initial Mn(II) was 55.06 ± 0.031 ppm, the concentration of Mn (II) ions with the MSP-TiO2 membrane of mass MSP-TiO2 were 20:1; 20:3; 20:5; 20:7; 20:9 respectively 36.47±0.00; 44.16±1.15; 44.31±1.04; 44.94±0.94; 42.27±2.61 ppm. The percentage of decrease concentration of Mn (II) ion are 34.19±0.44%; 21.37±0.43%; 20.94±0.85%; 19.24±0.86%; and 19.66±0.86%. The highest percentage decrease in Mn (II) ion concentration was 34.15±0.44% in the variation of mass MSP-TiO2 20:1. This study concludes that the MSP-TiO2 membrane has the potential to reduce the concentration of Mn (II) ions in water.

References

Prayoga, A., Ramdhani, Y., Mubarok, A. & Topiq, S., Pengukur Tingkat Kekeruhan Keasaman Dan Suhu Air Menggunakan Mikrokontroler Atmega328p Berbasis Android. J. Inform., 5(2): 248–254 (2018).

Menteri Kesehatan Republik Indonesia., Peraturan Menteri Kesehatan Republik Indonesia Nomor 32 Tahun 2017 Tentang Standar Baku Mutu Kesehatan Lingkungan Dan Persyaratan Kesehatan Air Untuk Keperluan Higiene Sanitasi, Kolam Renang, Solus Per Aqua dan Pemandian Umum. Peratur. Menteri Kesehat. Republik Indones., 1–20 (2017).

Aba, L., Bahrin. & Armid., Pengolahan Air Sumur Gali Dengan Metode Aerafiltrasi Menggunakan Aerator Gelembung Dan Saringan Pasir Cepat Untuk Menurunkan Kadar Besi (Fe) Dan Mangan (Mn). J. Apl. Fiiska, 13(02): 38–47 (2017).

Nughroho, B., Penurunan kadar Mn2+ dalam air dengan variasi konsentrasi Zeolit ZSM-5 dan variasi lama perendaman. Universitas Muhammadiyah Semarang, (2015).

Munfiah, S., Nurjazuli. & Setiani, O., Kualitas Fisik dan Kimia Air Sumur Gali dan Sumur Bor di Wilayah Kerja Puskesmas Guntur II Kabupaten Demak. J. Kesehat. Lingkung. Indones., 12(2): 154–159 (2013).

Fuad, H., Mukaromah, A. H. & Wardoyo, F. A., Penurunan Kadar Ion Mangan (II) Dalam Air Dengan Penambahan Serbuk Zeplit ZSM-5 Berdasarkan Variasi pH Larutan. Univ. Muhammadiyah Semarang, 1: 543–548 (2018).

Saputri, M. J., Mukaromah, A. H. & Yusrin., Sintesis Membran Zeolit Zsm-5 Secara Coating Pada Suhu 90°C Berdasarkan Variasi Jenis Ukuran Kasa Dalam Menurunkan Kadar Gas. Pros. Semin. Nas. Int., 1(1): (2017).

Alfiani, Y., Mukaromah, A. H. & Sulistyaningtyas, A. R., Photodegradation O Cr

(VI) In Various Concentration Of ZSM-5 Impregnated TiO2. Semin. Nas. Edusainstek, 84–92 (2018).

Faridah, F., Mukaromah, A. H. & Sulistyaningtyas, A. R., Photocatalytic Degradation Cr (VI) By ZSM-5 Impregnated TiO2 In Various UV-Irradiation Time. Semin. Nas. Edusainstek, 47–53 (2018).

Nurprihandayani, S., Ethica, S. N. & Mukaromah, A. H., Utilization Of TiO₂ Impregnated Zeolit-ZSM-5 To Decrease Concentration Of CR (VI) In Solution At pH Variance. Int. Semin. Educ. Dev. Asia, (2018).

Mukaromah, A. H., Chasanah, U., Assyifa, I. R., Mifbakuddin. & Sinto Dewi, S., Utilization of ZSM-5/TiO2 Powder and Membrane to Reduce Concentration Cu (II) and Cr (VI) Ions in Water. IOP Conf. Ser. Mater. Sci. Eng., 846(1): (2020).

Yusrin., Mukaromah, A. H. & Wahyuni, E. T., Penurunan Kadar Fe Dalam Air Dengan Biji Kelor (Moringa oleifera). Pros. Semin. Nas., 654–658 (2015).

Nugroho, B. A., Miswadi, S. S. & Santosa, N. B., Penggunaan Serbuk Biji Kelor Untuk Menurunkan Kadar Pb, Kekeruhan Dan Intensitas Warna. Indones. J. Chem. Sci., 3(3): (2014).

Abja, R., Mukaromah, A. H. & Wardoyo, F. A., Penurunan Kadar Nitrit dalam Air Menggunakan Arang Aktif Biji Kelor Reduction Nitrite Value in Water Using Activated Charcoal Moringa Seeds. Univ. Muhammadiyah Semarang, 17(1): 28–32 (2020).

Fuadi, D. A., Penurunan Ion Mangan (Mn) Dalam Air Dengan Serbuk Gergaji Kayu Jati (Tectona Grandis). (82): (2018).

Rosariawari, F., Masduki, A. & Hadi, W., Proses Fotokatalis Untuk Penyisihan E.coli Dengan Kombinasi TiO2, Karbon Aktif dan Sinar UV. J. Ilm. Tek. Lingkung., 4(1): 27–36 (2012).

Fauzi, W. A., Simpen, I. N. & W.Sudiarta, I., Sintesis Dan Karakterisasi Zeolit-TiO2 Serta Pemanfaatannya Sebagai Fotokatalis Untuk Degradasi Rhodamin B. (2017).

Marhaini., Legiso. & Rochyani, N., Application of Membran Polyvinylidene fluoride (PVDF) Synthesis Blending TiO2-Serbuk Kelor (Moringa Oleifera) Seed on Coal Wastewater Treatment. Int. J. Environ. Chem., 3(1): 1–6 (2019).

Sari, E. K., Wahyuni, E. T. & Aprilita, N. H., Pengaruh Ion Cu (II) dan Ion Ni (II) Terhadap Efektivitas Fotoreduksi Ion Cr (IV) Terkatalis TiO2. Berk. MIPA, 24(2): 136–148 (2014).

Kong, C., Lu, J., Yang, J. & Wang, J., Preparation of silicalite-1 membranes on stainless steel supports by a two-stage varying-temperature in situ synthesis. J. Memb. Sci., 285(1–2): 258–264 (2006).

Rustiah, W. & Andriani, Y., Menurunkan Kadar COD dan BOD pada Air Limbah Jasa Laundry Analysis of Kelor Seed Powder (Moringa oleifera , Lamk) in Reducing COD and BOD Contents on Wastewater Services Laundry Penentuan COD dengan Metode Refluks Tertutup. J. Chem., 5(2): 96–100 (2018).

Mukaromah, A. H., Wardoyo, F. A. & A. A, A., The Potential of Moringa oliefera Seed Powder (Msp) as a Substitute for ZSM-5 of Msp/TiO2 to Reduce Cu(II) Ion Concentration on Batik Industrial Waste in Pekalongan. 1st Int. Conf. Educ. Sci. Technol. FMIPA, 3(1): (2020).

Bertus, M. Y. P., Suherman. & Sabang, S. M., Karakterisasi FTIR Poliblend Adsorben Serbuk Biji Buah Kelor (Moringa oleifera) Dan Cangkang Ayam RAS untuk Pengolahan Air Gambut di Daerah Palu Barat. J. Akad. Kim., 3(1): 243–251 (2014).

Mukaromah, A. H., Efektivitas Fotodegradasi P-Klorofenol Dengan Katalis TiO2. J. Litbang Univ. Muhammadiyah Semarang, 2(2): 37–44 (2012).

Hoffman, M.R., Martin, S.T., Choi, W. and Bahneman, D.W. Environmental Application of Semiconductor Photocatalysis. J. Chem. Rev. 69-96 (1995)

Downloads

Published

2023-03-24

How to Cite

Mukaromah, A. H., Wardoyo, F. A. ., Sulistyaningtyas, A. R. ., & Ghazi, H. N. (2023). Decreasing of Mangan (II) in The Water Using Membrane of Moringa Seed Powder-TiO2 with Variation of Mass TiO2. Jurnal Riset Kimia, 14(1), 1–11. https://doi.org/10.25077/jrk.v14i1.512

Issue

Section

Articles

Citation Check