Kajian Penggunaan Carbon Black N990 sebagai Bahan Pengisi Kompon Karet Alam: Sifat Dinamik, Kestabilan Termal, dan Ketahanan Panas
DOI:
https://doi.org/10.25077/jrk.v14i1.560Keywords:
rubber, Carbon Black N990, dynamic, thermal stability, heat resistanceAbstract
The manufacture of vibration damping material from natural rubber (NR) required an increase in dynamic properties, thermal stability, and resistance to heat. Using the Carbon Black N990 as a filler in NR vulcanizates can potentially increase on these properties. This research aims to study the effect of using Carbon Black N990 on dynamic properties, thermal stability, and aging resistance to heat in NR vulcanizates. The dynamic properties of NR vulcanizates were determined by Rubber Process Analyzer (RPA), while the thermal stability properties were studied by TGA, and heat resistance was determined by the thermal aging test. The RPA test results showed that adding 50 phr Carbon Black N990 in the NR compound could increase the value of the complex shear modulus to 65%. Furthermore, the results of the TGA test showed that the thermal stability properties of unfilled NR vulcanizates were better than that of NR vulcanizates containing Carbon Black N990. Unfilled NR vulcanizates were heat stable up to 353oC, while NR vulcanizates containing 15, 30, and 50 parts per hundred rubber (phr) Carbon Black N990, respectively, were heat stable up to 348.1oC, 348oC, and 349oC. Based on the requirements of ISO 4632-1, it showed that the NR compound containing Carbon Black N990 has good heat resistance properties. The NR compound formula contains 30 phr Carbon Black N990 showing good dynamic properties and heat resistance in accordance with EN 15129 requirements so that it has the potential to be used as a vibration damping material for earthquake-resistant structures.
References
Maciejewska, M. & Sowińska, A., Influence of fillers and ionic liquids on the crosslinking and performance of natural rubber biocomposites. Polymers (Basel)., 13(10): (2021).
Marhoon, I. I., Mechanical And Physical Properties Of Polyurethane Composites Reinforced With Carbon Black N990 Particles. Int. J. Jof Sci. Technol. Res., 6(08): 225–228 (2017).
Hujare, P. P. & Sahasrabudhe, A. D., Experimental Investigation of Damping Performance of Viscoelastic Material Using Constrained Layer Damping Treatment. Procedia Mater. Sci., 5: 726–733 (2014).
Halladay, B. J. R. & Jaglowski, K. T., Sources of hysteresis in rubber compounds Technical. 13–17 (2017).
Hentschke, R., The P ayne effect revisited. 11(4): 278–292 (2017).
Le Cam, J. B., Energy storage due to strain-induced crystallization in natural rubber: The physical origin of the mechanical hysteresis. Polymer (Guildf)., 127: 166–173 (2017).
Shi, G., Wang, W., Lu, H., Wang, G., Yang, F. & Rui, X., Study of crosslink structure and dynamic mechanical properties of magnetorheological elastomer: Effect of vulcanization system. J. Intell. Mater. Syst. Struct., 30(8): 1189–1199 (2019).
Su, C., Zhao, C., Xu, L. & Zhang, C., Effects of chemical structure of phenolic resin on damping properties of acrylate rubber-based blends. J. Macromol. Sci. Part B Phys., 54(2): 177–189 (2015).
Lei, T., Zhang, Y. W., Kuang, D. L. & Yang, Y. R., Preparation and properties of rubber blends for high-damping-isolation bearings. Polymers (Basel)., 11(8): (2019).
Abedi Koupai, S., Bakhshi, A. & Valadoust Tabrizi, V., Experimental investigation on effects of elastomer components on dynamic and mechanical properties in seismic isolator compounds. Constr. Build. Mater., 135: 267–278 (2017).
Mohamad, N., Yaakub, J., Ab Maulod, H. E., Jeefferie, A. R., Yuhazri, M. Y., Lau, K. T., Ahsan, Q., et al., Vibrational damping behaviors of graphene nanoplatelets reinforced NR/EPDM nanocomposites. J. Mech. Eng. Sci., 11(4): 3274–3287 (2017).
Wang, Y., Liao, L., Lin, H., Zhang, F., Zhong, J., Xu, K. & Peng, Z., Damping Properties of Natural rubber/ Epoxidized Natural Rubber composites with different fillers. (January): (2018). doi:10.2991/ifeesm-17.2018.145
Wang, J., Zhao, X., Wang, W., Geng, X., Zhang, L., Guo, B., Nishi, T., et al., Significantly Improving Strength and Damping Performance of Nitrile Rubber via Incorporating Sliding Graft Copolymer. Ind. Eng. Chem. Res., 57(49): 16692–16700 (2018).
Li, J. C., Zhang, H. S., Zhao, X. Y., Jiang, J. G., Wu, Y. X., Lu, Y. L., Zhang, L. Q., et al., Development of high damping natural rubber/butyl rubber composites compatibilized by isobutylene-isoprene block copolymer for isolation bearing. Express Polym. Lett., 13(8): 686–696 (2019).
Murniati, R., Rahmayanti, H. D., Utami, F. D., Cifriadi, A., Iskandar, F. & Abdullah, M., Effects of magnetically modified natural zeolite addition on the crosslink density, mechanical, morphological, and damping properties of SIR 20 natural rubber reinforced with nanosilica compounds. J. Polym. Res., 27(2): (2020).
Ma, R., Zhang, X., Liu, C. & Wu, W., Hindered phenol-mediated damping of polyacrylate rubber: Effect of hydrogen bonding strength on the damping properties. J. Polym. Eng., 39(7): 642–652 (2019).
Andriani, W., Cifriadi, A. & Puspitasari, S., Pengaruh Jenis Arang Hitam Terhadap Sifat Mekanik Komposit Karet Alam Pada Vulkanisat Elastomer Bantalan Jembatan. J. Penelit. Karet, (October): 65–74 (2019). doi:10.22302/ppk.jpk.v37i1.606
Gao, T., Xie, R., Zhang, L., Gui, H. & Huang, M., Use of Rubber Process Analyzer for Characterizing the Molecular Weight Parameters of Natural Rubber. Int. J. Polym. Sci., 2015: (2015).
Yunus, N. A., Mazlan, S. A., Ubaidillah., Abdul Aziz, S. A., Shilan, S. T. & Abdul Wahab, N. A., Thermal stability and rheological properties of epoxidized natural rubber-based magnetorheological elastomer. Int. J. Mol. Sci., 20(3): 1–19 (2019).
Hiranobe, C. T., Ribeiro, G. D., Torres, G. B., Dos Reis, E. A. P., Cabrera, F. C., Job, A. E., Paim, L. L., et al., Cross-linked density determination of natural rubber compounds by different analytical techniques. Mater. Res., 24(S1): 1–9 (2021).
Larpkasemsuk, A., Raksaksri, L., Chuayjuljit, S., Chaiwutthinan, P. & Boonmahitthisud, A., Effects of sulfur vulcanization system on cure characteristics, physical properties and thermal aging of epoxidized natural rubber. J. Met. Mater. Miner., 29(1): 49–57 (2019).
Alshabatat, N. & Abouel-Kasem, A., The Effects of Sulfur Content on the Mechanical Properties of Nitrile Butadiene Rubber with Different Aging Conditions. Jordan J. Mech. Ind. Eng., 15(4): 387–393 (2021).
Kim, D. Y., Park, J. W., Lee, D. Y. & Seo, K. H., Correlation between the crosslink characteristics and mechanical properties of natural rubber compound via accelerators and reinforcement. Polymers (Basel)., 12(9): 1–14 (2020).
Han, S., Gu, B., Kim, S., Kim, S., Mun, D., Morita, K., Kim, D., et al., Effect of sulfur variation on the vulcanizate structure of silica-filled styrene-butadiene rubber compounds with a sulfide–silane coupling agent. Polymers (Basel)., 12(12): 1–14 (2020).
Hayeemasae, N. & Masa, A., Relationship between stress relaxation behavior and thermal stability of natural rubber vulcanizates. Polimeros, 30(2): (2020).
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