Pengaruh Perbandingan Massa Silikon/Silika terhadap Karbon pada Kinerja Anode Baterai Litium Ion dari Sekam Padi

Authors

  • Achmad Rochliadi Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia https://orcid.org/0009-0003-6911-4030
  • Mohammad Alief Ramdhan Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
  • Aep Patah Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia

DOI:

https://doi.org/10.25077/jrk.v14i2.624

Keywords:

rice husk, silicon/silica/carbon composite, lithium ion battery

Abstract

This study aims to investigate the possible utilization of silica (SiO2) and silicon (Si) derived from rice husks as anode materials in lithium-ion batteries (LIBs). SiO2 and Si have impressive theoretical capacities of 1965 and 4200 mAh/g, respectively. However, their direct use as LIBs anodes faces challenges such as substantial volume changes during battery charging and discharging, as well as low electrical conductivity. Consequently, a common approach is to create nanostructures of SiO2 and Si, such as nanoparticles, nanowires, and nanotubes, and combine them with conductive matrices like carbon-based materials. In this study, the Si/SiO2/C composite was synthesized from rice husks, taking into account the mass ratio of Si/SiO2 to C. The process involved first separating SiO2 and C from rice husks and then synthesizing the composite using the ball mill method and activated molten salt aluminothermic reduction (AlCl3/NaCl). X-ray Diffraction (XRD) analysis confirmed the successful synthesis of the composite, as indicated by characteristic peaks of the constituent compounds. Scanning Electron Microscope (SEM) imaging showed non-uniform morphology with varying particle sizes. Tests results demonstrated that the Si/SiO2/C composite with a 3:1 ratio exhibited the most promising performance as a LIB anode, maintaining a high capacity of 280.48 mAh/g with a Coulombic Efficiency (CE) of 99% after 50 testing cycles. These findings suggest that silica and silicon compounds derived from rice husks hold great potential as efficient and durable anode materials for LIBs applications.

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Published

2023-10-17

How to Cite

Rochliadi, A., Ramdhan, M. A. ., & Patah, A. (2023). Pengaruh Perbandingan Massa Silikon/Silika terhadap Karbon pada Kinerja Anode Baterai Litium Ion dari Sekam Padi. Jurnal Riset Kimia, 14(2), 226–238. https://doi.org/10.25077/jrk.v14i2.624

Issue

Vol. 14 No. 2 (2023): September

Section

Articles

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