Pemanfaatan Lumpur Lapindo sebagai Sumber Silika Magnetik untuk Adsorpsi Tumpahan Crude Palm Oil

Authors

  • Wihda Zuhara Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Diponegoro, Indonesia
  • Rahmad Nuryanto Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Diponegoro, Indonesia https://orcid.org/0000-0003-0519-8864
  • Retno Ariadi Lusiana Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Diponegoro, Indonesia
  • Lisna Efiyanti Center for Biomass and Bioproduct Research, National Research and Innovation Agency, Indonesia

DOI:

https://doi.org/10.25077/jrk.v15i1.658

Keywords:

Adsorption, CTAB, Lapindo Mud, Magnetite, Microemulsion

Abstract

In this paper, synthesis of silica magnetite adsorbent has been carried out from Lapindo Mud silica and magnetite (Fe3O4) using the template Cetyltrimethylammonium bromide (CTAB) through a microemulsion process. This research aims to determine the adsorption ability of magnetic silica material as an adsorbent for Crude Palm Oil (CPO) with varying contact times of 10, 20, 30, 60, 90 minutes and an adsorbate concentration of 0,2, 0,4, 0,6, 0,8 and 1 gram. Silica is obtained from Lapindo Mud extraction using the acid leaching method using HCl. Magnetite was prepared by mixing ferric chloride and ferrous chloride salts with an alkaline base. Synthesis of magnetic silica adsorbent using CTAB and 1-butanol as a surfactant and co-surfactant, respectively. The characterization results from FTIR and SEM-EDX data identified the presence of silanol (Si-OH) and Fe-O groups, magnetic silica adsorbent showed an irregular morphological pattern, the size tended to be heterogeneous, contained Fe, O and Si elements. The XRD results show that there are peaks in the (200), (311) and (440) planes, the GSA results show that the pore surface area is 37.048 m2/g, the total pore volume is 0.321 cm3/g and the pore diameter is 33.907 nm, which indicates that the pores have a mesoporous structure. Based on this research, the optimum contact time is 60 minutes with adsorption kinetics following the pseudo-second order and Langmuir isotherm with an adsorption capacity of 1.76 mg/g.

References

Firmansyah, M. D., Ismanto, A., Wulandari, S. Y., Widiaratih, R., Rifai, A. & Atmodjo, W., Pemodelan Sebaran Tumpahan Minyak di Perairan Karawang, Jawa Barat. Bul. Oseanografi Mar., 10(2): 200–212 (2021).

Dai, X., Lv, J., Yan, G., Chen, C., Guo, S. & Fu, P., Bioremediation of intertidal zones polluted by heavy oil spilling using immobilized laccase-bacteria consortium. Bioresour. Technol., 309(February): 123305 (2020).

Stanley, M., Palace, V., Grosshans, R. & Levin, D. B., Floating treatment wetlands for the bioremediation of oil spills: A review. J. Environ. Manage., 317(April): 115416 (2022).

Fritt-Rasmussen, J., Wegeberg, S., Lassen, P., Wilms, L. B., Renvald, L., Larsen, M. B., Geertz-Hansen, O., et al., Coastline in-situ burning of oil spills, analysis of a Greenland field experiment. J. Hazard. Mater., 441(September 2022): (2023).

Nwadiogbu, J. O., Ajiwe, V. I. E. & Okoye, P. A. C., Removal of crude oil from aqueous medium by sorption on hydrophobic corncobs: Equilibrium and kinetic studies. J. Taibah Univ. Sci., 10(1): 56–63 (2016).

Songsaeng, S., Thamyongkit, P. & Poompradub, S., Natural rubber/reduced-graphene oxide composite materials: Morphological and oil adsorption properties for treatment of oil spills. J. Adv. Res., 20: 79–89 (2019).

Masoumi, F., Safari, S., Khoshbin, R. & Karimzadeh, R., Utilization of agricultural waste (rice husk) in synthesis of TS-1 zeolite as a support for NiMo nanocatalyst employed in hydrodesulfurization of heavy oil. Adv. Powder Technol., 34(9): 104134 (2023).

Ugochukwu, U. C., Jones, M. D., Head, I. M., Manning, D. A. C. & Fialips, C. I., Biodegradation and adsorption of crude oil hydrocarbons supported on ‘homoionic’ montmorillonite clay minerals. Appl. Clay Sci., 87: 81–86 (2014).

Peng, D., Li, H., Li, W. J. & Zheng, L., Biosorbent with superhydrophobicity and superoleophilicity for spilled oil removal. Ecotoxicol. Environ. Saf., 209: 111803 (2021).

Kumar, N., Amritphale, S. S., Matthews, J. C. & Lynam, J. G., Oil spill cleanup using industrial and agricultural waste-based magnetic silica sorbent material: a green approach. Green Chem. Lett. Rev., 14(4): 632–639 (2021).

Hastuti, S., Nuryono. & Kuncaka, A., L-arginine-modified silica for adsorption of gold(III). Indones. J. Chem., 15(2): 108–115 (2015).

Arefieva, O. D., Vasilyeva, M. S., Zemnukhova, L. A., Opra, D. P., Nikolaeva, D. A., Tkachev, V. V. & Shlyk, D. H., Effect of silica source on photocatalytic properties of Bi2O3/Bi2SiO5 heterostructure. J. Bioresour. Bioprod., 8(2): 176–186 (2023).

Lü, T., Qi, D., Zhang, D., Lin, S., Mao, Y. & Zhao, H., Facile synthesis of N-(aminoethyl)-aminopropyl functionalized core-shell magnetic nanoparticles for emulsified oil-water separation. J. Alloys Compd., 769: 858–865 (2018).

Ciptawati, E., Hilfi Azra Dzikrulloh, M., Oki Septiani, M., Rinata, V., Ainur Rokhim, D., Azfa Fauziyyah, N., et al., Analisis Kandungan Mineral dari Lumpur Panas Sidoarjo sebagai Potensi Sumber Silika dan Arah Pemanfaatannya. IJCA (Indonesian J. Chem. Anal., 5(1): 18–28 (2022).

Dewi, W. P., Haryati, T., Suwardiyanto, S., Sulistiyo, Y. A. & Andarini, N., Variasi Penambahan CTABr Sebagai Template Terhadap Pembentukan TiO2 Anatase Dari Senyawa Natrium Titanat dan Aplikasinya Sebagai Fotokatalis. Berk. Sainstek, 7(2): 43 (2019).

Tyrode, E., Rutland, M. W. & Bain, C. D., Adsorption of CTAB on hydrophilic silica studied by linear and nonlinear optical spectroscopy. J. Am. Chem. Soc., 130(51): 17434–17445 (2008).

Bi, Z., Liao, W. & Qi, L., Wettability alteration by CTAB adsorption at surfaces of SiO 2 film or silica gel powder and mimic oil recovery. Appl. Surf. Sci., 221(1–4): 25–31 (2004).

Tatarchuk, T., Soltys, L. & Macyk, W., Magnetic adsorbents for removal of pharmaceuticals: A review of adsorption properties. J. Mol. Liq., 384(May): 122174 (2023).

Efiyanti, L., Trisunaryanti, W., Bahri, S., Ni’mah, Y. L., Wulandari, N. M. & Sumbogo, S. D., Synthesis of Mesoporous Silica From Beach Sand Using Variation of Cetyl Trimethyl Ammonium Bromide (CTAB) . Proc. 3rd KOBI Congr. Int. Natl. Conf. (KOBICINC 2020), 14(Kobicinc 2020): 374–381 (2021).

Nuryanto, R., Trisunaryanti, W. & Triyono., Variation of gelatin amount as template for mesoporous silica-alumina synthesis based on lapindo mud. Asian J. Chem., 32(7): 1576–1580 (2020).

Zhou, J., Sui, H., Ma, J., Li, X., Al-Shiaani, N. H. A. & He, L., Fast demulsification of oil-water emulsions at room temperature by functionalized magnetic nanoparticles. Sep. Purif. Technol., 274(January): 118967 (2021).

Asgari, M., Soleymani, M., Miri, T. & Barati, A., A robust method for fabrication of monodisperse magnetic mesoporous silica nanoparticles with core-shell structure as anticancer drug carriers. J. Mol. Liq., 292: 111367 (2019).

Abhishek, R., Hamouda, A. A. & Abdulhameed, F. M., Adsorption kinetics and enhanced oil recovery by silica nanoparticles in sandstone. Pet. Sci. Technol., 37(12): 1363–1369 (2019).

Danalıoğlu, S. T., Bayazit, Ş. S., Kerkez Kuyumcu, Ö. & Salam, M. A., Efficient removal of antibiotics by a novel magnetic adsorbent: Magnetic activated carbon/chitosan (MACC) nanocomposite. J. Mol. Liq., 240: 589–596 (2017).

Bayramoglu, G. & Arica, M. Y., Star type polymer grafted and polyamidoxime modified silica coated-magnetic particles for adsorption of U(VI)ions from solution. Chem. Eng. Res. Des., 147: 146–159 (2019).

Hu, C., Zheng, H., Zhao, R., Zhang, S., Sun, Q., Jiang, J. & Sun, Y., Structural design of a floating-magnetically responsive silica adsorbent and efficient removal of dyes. J. Clean. Prod., 302: 126985 (2021).

Paramesti, C., Trisunaryanti, W., Sudiono, S., Triyono, T., Larasati, S., Santoso, N. R. & Fatmawati, D. A., The influence of metal loading amount on ni/mesoporous silica extracted from lapindo mud templated by ctab for conversion of waste cooking oil into biofuel. Bull. Chem. React. Eng. Catal., 16(1): 22–30 (2021).

Amin, K. F., Gulshan, F., Asrafuzzaman, F. N. U., Das, H., Rashid, R. & Manjura Hoque, S., Synthesis of mesoporous silica and chitosan-coated magnetite nanoparticles for heavy metal adsorption from wastewater. Environ. Nanotechnology, Monit. Manag., 20(January): 100801 (2023).

Banihashemi, M., Dalali, N., Sehati, N. & Farajmand, B., Decoration of Fe3O4@SiO2@ZnO as a high performance nanosorbent on a stir bar microextraction device for preconcentration and determination of cadmium in real water samples. Microchem. J., 154(August 2019): 104599 (2020).

Andini, A. M., Azmiyawati, C. & Darmawan, A., Effect of pH on the Synthesis of Silica Sol-Gel Tetraethylorthosilicate-Trimethylchlorosilan (TEOS-TMCS). J. Kim. Sains dan Apl., 25(11): 394–398 (2022).

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Published

2024-03-29

How to Cite

Zuhara, W., Nuryanto, R., Lusiana, R. A., & Efiyanti, L. (2024). Pemanfaatan Lumpur Lapindo sebagai Sumber Silika Magnetik untuk Adsorpsi Tumpahan Crude Palm Oil. Jurnal Riset Kimia, 15(1), 112–122. https://doi.org/10.25077/jrk.v15i1.658

Issue

Vol. 15 No. 1 (2024): March

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