Sintesis dan Karakterisasi Solid Polymer Electrolyte (SPE) Berbasis Nanofiber Selulosa untuk Menunjang Baterai Litium Berdensitas Tinggi dan Ramah Lingkungan

Authors

  • Ahmad Ali Muckharom Departemen Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang, Indonesia
  • Rizky Putra Adithia Departemen Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang, Indonesia
  • Putri Diah Wahyu Karimah Departemen Kimia, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang, Indonesia
  • Tabah Ditalistya Departemen Kimia, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang, Indonesia
  • Rahmad Nuryanto Departemen Kimia, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang, Indonesia
  • Lisa Efiyanti Research Center for Biomass and Bioproduct, National Research and Development Agency Nanotechnology Laboratory, Integrated Laboratory of Diponegoro University, Semarang, Indonesia

DOI:

https://doi.org/10.25077/jrk.v15i2.672

Keywords:

cellulose nanofiber, lithium battery, solid polymer electrolyte

Abstract

Lithium battery as one of the energy storage has two important elements, namely electrodes and electrolyte. Electrolyte is a part of the battery element that has undergone many developments. In this study, the manufacture of electrolytes in the form of Solid Polymer Electrolyte (SPE) was carried out by utilizing the abundant availability of nata de coco. The nanofibrous cellulose structure in Bacterial Cellulose (BC) nata de coco has the advantages of good porosity, flexibility in surface functionality, compact porous structure that provides abundant ion pathways and hetero atoms (oxygen atoms) with free electron pairs that facilitate ionic conduction. The SPE synthesis process was carried out by varying the soaking time of nata de coco in ethanol, namely 1, 2 and 3 days to determine the structure with optimal results. FTIR characterization results show the synthesis of cellulose nanofiber has the same groups as commercial cellulose groups in the form of O-H, C-H, C=O and C-O. CV characterization results show the SPE electrolyte has good redox properties, especially in the 2-day variation with the highest specific capacitance. The EIS test showed the lowest resistance in the 1-day variation sample with a conductivity of 0.017 ohm-1.

References

I. Boumanchar et al., “Municipal solid waste higher heating value prediction from ultimate analysis using multiple regression and genetic programming techniques,” Waste Management and Research, vol. 37, no. 6, pp. 578–589, Jun. 2019, doi: 10.1177/0734242X18816797.”

M. Karnan, K. Subramani, P. K. Srividhya, and M. Sathish, “Electrochemical Studies on Corncob Derived Activated Porous Carbon for Supercapacitors Application in Aqueous and Non-aqueous Electrolytes,” Electrochim Acta, vol. 228, pp. 586–596, Feb. 2017, doi: 10.1016/j.electacta.2017.01.095.

Y. Guo, L. Zhang, Y. Liu, and S. Guo, “Almond Shell-Derived Carbons under Low-Temperature Activation with UltraHigh Surface Area and Superior Performance for Supercapacitors,” ChemistrySelect, vol. 4, no. 43, pp. 12472–12478, Nov. 2019, doi: 10.1002/slct.201903480.

P. U. Nzereogu, A. D. Omah, F. I. Ezema, E. I. Iwuoha, and A. C. Nwanya, “Anode materials for lithium-ion batteries: A review,” Applied Surface Science Advances, vol. 9. Elsevier B.V., Jun. 01, 2022. doi: 10.1016/j.apsadv.2022.100233.

F. A. Perdana, “Baterai Lithium,” INKUIRI: Jurnal Pendidikan IPA, vol. 9, no. 2, p. 113, Apr. 2021, doi: 10.20961/inkuiri.v9i2.50082.

J. Wang, J. He, D. Kan, K. Chen, M. Song, and W. Huo, “MXene Film Prepared by Vacuum-Assisted Filtration: Properties and

Applications,” Crystals, vol. 12, no. 8. MDPI, Aug. 01, 2022. doi: 10.3390/cryst12081034.

K. Borzutzki, J. Thienenkamp, M. Diehl, M. Winter, and G. Brunklaus, “Fluorinated polysulfonamide based single ion conducting room temperature applicable gel-type polymer electrolytes for lithium ion batteries,” J Mater Chem A Mater, vol. 7, no. 1, pp. 188–201, 2019, doi: 10.1039/c8ta08391f.

Y. Gu, S. Fang, L. Yang, and S. ichi Hirano, “A safe electrolyte for high-performance lithium-ion batteries containing lithium

difluoro(oxalato)borate, gammabutyrolactone and non-flammable hydrofluoroether,” Electrochim Acta, vol. 394, Oct. 2021, doi: 10.1016/j.electacta.2021.139120.

P. Fan et al., “High Performance Composite Polymer Electrolytes for Lithium-Ion Batteries,” Advanced Functional Materials, vol. 31, no. 23. John Wiley and Sons Inc, Jun. 01, 2021. doi: 10.1002/adfm.202101380.

S. Chen, K. Wen, J. Fan, Y. Bando, and D. Golberg, “Progress and future prospects of high-voltage and high-safety electrolytes in

advanced lithium batteries: From liquid to solid electrolytes,” Journal of Materials Chemistry A, vol. 6, no. 25. Royal Society of Chemistry, pp. 11631–11663, 2018. doi: 10.1039/c8ta03358g.

Y. L. Ni’Mah, M. Y. Cheng, J. H. Cheng, J. Rick, and B. J. Hwang, “Solid-state polymer nanocomposite electrolyte of TiO2/PEO/NaClO4 for sodium ion batteries,” J Power Sources, vol. 278, pp. 375–381, Mar. 2015, doi: 10.1016/j.jpowsour.2014.11.047.

D. Lasrado, S. Ahankari, and K. Kar, “Nanocellulose-based polymer composites for energy applications—A review,” Journal of Applied Polymer Science, vol. 137, no. 27. John Wiley and Sons Inc., Jul. 15, 2020. doi: 10.1002/app.48959.

Q. Sabrina et al., “Preparation and characterization of nanofibrous cellulose as solid polymer electrolyte for lithium-ion

battery applications,” RSC Adv, vol. 11, no. 37, pp. 22929–22936, Jun. 2021, doi: 10.1039/d1ra03480d.

Downloads

Published

2024-09-30

How to Cite

Muckharom, A. A. ., Adithia, R. P. ., Karimah, P. D. W. ., Ditalistya, T. ., Nuryanto, R. ., & Efiyanti, L. (2024). Sintesis dan Karakterisasi Solid Polymer Electrolyte (SPE) Berbasis Nanofiber Selulosa untuk Menunjang Baterai Litium Berdensitas Tinggi dan Ramah Lingkungan. Jurnal Riset Kimia, 15(2), 1–10. https://doi.org/10.25077/jrk.v15i2.672

Issue

Vol. 15 No. 2 (2024): September

Section

Articles

Citation Check

License

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.

1. License

The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License. 

2. Author(s)' Warranties

The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).

3. User Rights

Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.

4. Rights of Authors

Authors retain all their rights to the published works, such as (but not limited to) the following rights;

  • Copyright and other proprietary rights relating to the article, such as patent rights,
  • The right to use the substance of the article in own future works, including lectures and books,
  • The right to reproduce the article for own purposes,
  • The right to self-archive the article,
  • The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.

5. Co-Authorship

If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.