Pengaruh Compatibilizer Polyvinyl Alcohol-graft-Maleic Anhydride (PVA-g-MAH) terhadap Karakteristik Plastik Degradable Berbasis Pati Sagu dan Pati Biji Nangka

Authors

  • Rozanna Dewi Program Studi Teknik Kimia, Fakultas Teknik, Universitas Malikussaleh, Lhokseumawe, Indonesia
  • Zulnazri Zulnazri Program Studi Teknik Kimia, Fakultas Teknik, Universitas Malikussaleh, Lhokseumawe, Indonesia
  • Novi Sylvia Program Studi Teknik Kimia, Fakultas Teknik, Universitas Malikussaleh, Lhokseumawe, Indonesia
  • Medyan Riza Program Studi Teknik Kimia, Fakultas Teknik, Universitas Syiah Kuala, Banda Aceh, Indonesia

DOI:

https://doi.org/10.25077/jrk.v15i2.695

Keywords:

degradable plastic, PVA-g-MAH, compatibilizer, sago starch, jackfruit seed starch

Abstract

Degradable plastics may be employed as a substitute for conventional plastics in various commercial applications. Plastics made from starch and PVA-g-MAH are biodegradable. This research uses sago and jackfruit starch, a maleic anhydride compatibilizer, and PVA to make degradable plastics stronger. The research method consists of several stages, making sago starch and jackfruit seed starch, preparing degradable plastic synthesis, and testing the resulting degradable plastic. The test of mechanical characteristics of degradable plastics carried out is the tensile strength test of 4.41 Mpa - 6.02 MPa on sago starch-based degradable plastic with PVA-g-MAH, while the tensile strength of 6.86 - 8.43 MPa on jackfruit seed starch-based degradable plastic with PVA-g-MAH. The test shows that the compound is hydrophilic, meaning it binds to water and is easily degraded by soil. The DSC thermogram shows that the plastic samples degrade when heated, both thermogram peaks occur which indicate physical changes. The swelling value obtained in sago starch degradable plastic with PVA-g-MAH is (28.14-72.17%) while in jackfruit seed starch degradable plastic, the swelling obtained ranges from (25.91-84.72%) showing a good result. Sago starch and jackfruit seed starch degradable plastics degraded in 6-18 days using PVA-g-MAH. Sago starch and jackfruit seed starch-based plastics using PVA-g-MA meet the ASTM 6400 standard for biodegradable plastics. The plastic should be able to biodegrade up to 60% within six months or 90% within one year.

References

Tanjung, D. A., Jamarun, N., Arief, S., Aziz, H., Ritonga, A. H. & Isfa, B., Influence of LLDPE-g-MA on Mechanical Properties, Degradation Performance, and Water Absorption of Thermoplastic Sago Starch Blends. Indones. J. Chem., 22(1): 171–178 (2022).

Falua, K. J., Pokharel, A., Babaei-Ghazvini, A., Ai, Y. & Acharya, B., Valorization of Starch to Biobased Materials: A Review. Polymers (Basel)., 14(11): 1–44 (2022).

Muhamad Saleh, E. R., Rakhman, K. A. & Samad, S., Synthesis of Biofoam From Sago Waste as a Biodegradable Food Storage Candidate. KnE Life Sci., 2022: 162–169 (2022).

Lusiana, S. W., Putri, D., Nurazizah, I. Z. & Bahruddin., Bioplastic Properties of Sago-PVA Starch with Glycerol and Sorbitol Plasticizers. J. Phys. Conf. Ser., 1351(1): (2019).

Dianursanti. & Khalis, S. A., The Effect of Compatibilizer Addition on Chlorella vulgaris Microalgae Utilization as a Mixture for Bioplastic. E3S Web Conf., 67: 2–6 (2018).

Guo, B., Zha, D., Li, B., Yin, P. & Li, P., Polyvinyl alcohol microspheres reinforced thermoplastic starch composites. Materials (Basel)., 11(4): 1–8 (2018).

Nagy, B., Miskolczi, N. & Eller, Z., Improving mechanical properties of pla/starch blends using masterbatch containing vegetable oil based active ingredients. Polymers (Basel)., 13(17): (2021).

Bátori, V., Lundin, M., Åkesson, D., Lennartsson, P. R., Taherzadeh, M. J. & Zamani, A., The effect of glycerol, sugar, and maleic anhydride on pectin-cellulose thin films prepared from orange waste. Polymers (Basel)., 11(3): (2019).

Shrestha, B., Chapain, K., Shah, S. & Pandit, R., Starch/ Polyvinyl Alcohol (PVA) Blend Bioplastics: Synthesis and Physicochemical Properties. J. Nepal Chem. Soc., 43(2): 103–109 (2023).

Dewi, R., Sylvia, N. & Riza, M., Characterization of Degradable Plastics from Sago and Breadfruit Starch-Based with Addition of Zinc Oxide (ZnO) Catalyst and Polyvinyl Alcohol (PVA). J. Kim. Sains dan Apl., 26(11): 427–436 (2023).

Elgharbawy, A. S., El Demerdash, A. G. M., Sadik, W. A., Kasaby, M. A., Lotfy, A. H. & Osman, A. I., Synthetic Degradable Polyvinyl Alcohol Polymer and Its Blends with Starch and Cellulose—A Comprehensive Overview. Polymers (Basel)., 16(10): (2024).

More, A. S., Sen, C. & Das, M., Development of Starch-Polyvinyl Alcohol (PVA) Biodegradable Film: Effect of Cross-Linking Agent and Antimicrobials on Film Characteristics. J. Appl. Packag. Res., 9(3): 1 (2017).

Mandei, J. H., The Use of Heat Moisture Treatment-Modified Sago Starch As a Substitute Ingredient for Dried Noodle Product. J. Penelit. Teknol. Ind., 8(Juni): 57–72 (2016).

Nguyen, T. K., That, N. T. T., Nguyen, N. T. & Nguyen, H. T., Development of Starch-Based Bioplastic from Jackfruit Seed. Adv. Polym. Technol., 2022: (2022).

Raj, A., Samuel, C. & Prashantha, K., Role of Compatibilizer in Improving the Properties of PLA/PA12 Blends. Front. Mater., 7(July): 1–12 (2020).

Yu, S., Zhang, Y., Hu, H., Li, J., Zhou, W., Zhao, X. & Peng, S., Effect of maleic anhydride grafted poly(lactic acid) on rheological behaviors and mechanical performance of poly(lactic acid)/poly(ethylene glycol) (PLA/PEG) blends. RSC Adv., 12(49): 31629–31638 (2022).

Poly, P., Combined Effect of Poly ( lactic acid ) -Grafted Maleic Anhydride Compatibilizer and Halloysite Nanotubes on Morphology and. (2023).

Dwi, T. & Matondang, S., Studies about Palm Sago Starch as a Filler to Make Biodegradable Packaging Material. 7(1): 163–175 (2017).

Aksit, A., Menzel, T., Aksit, M. & Altstädt, V., Properties of styrene-maleic anhydride copolymer compatibilized polyamide 66/poly (phenylene ether) blends: Effect of maleic anhydride concentration and copolymer content. Materials (Basel)., 13(5): (2020).

Navasingh, R. J. H., Gurunathan, M. K., Nikolova, M. P. & Królczyk, J. B., Sustainable Bioplastics for Food Packaging Produced from Renewable Natural Sources. Polymers (Basel)., 15(18): (2023).

Barrino, F., De La Rosa-Ramírez, H., Schiraldi, C., López-Martínez, J. & Samper, M. D., Preparation and Characterization of New Bioplastics Based on Polybutylene Succinate (PBS). Polymers (Basel)., 15(5): 1–15 (2023).

Kane, S. N., Mishra, A. & Dutta, A. K., Preface: International Conference on Recent Trends in Physics (ICRTP 2016). J. Phys. Conf. Ser., 755(1): (2016).

Tan, S. X., Andriyana, A., Ong, H. C., Lim, S., Pang, Y. L. & Ngoh, G. C., A Comprehensive Review on the Emerging Roles of Nanofillers Fabrication. Polymers (Basel)., 14(664): 1–27 (2022).

Li, M., Tian, X., Jin, R. & Li, D., Preparation and characterization of nanocomposite films containing starch and cellulose nanofibers. Ind. Crops Prod., 123(July): 654–660 (2018).

Ortega-Toro, R., López-Córdoba, A. & Avalos-Belmontes, F., Epoxidised sesame oil as a biobased coupling agent and plasticiser in polylactic acid/thermoplastic yam starch blends. Heliyon, 7(2): 1–8 (2021).

Dewi, R., Ibrahim, N., Sylvia, N., Abdullah, D. & Riza, M., Thermal behavior of modified thermoplastic starch (Tps) synthesized from sago (metroxylon sagu) with diphenylmethane diisocyanate and castor oil. Emerald Reach Proc. Ser., 1: 387–393 (2018).

Kowser, M. A., Hossain, S. M. K., Amin, M. R., Chowdhury, M. A., Hossain, N., Madkhali, O., Rahman, M. R., et al., Development and Characterization of Bioplastic Synthesized from Ginger and Green Tea for Packaging Applications. J. Compos. Sci., 7(3): 1–17 (2023).

Majder-Łopatka, M., Węsierski, T., Ankowski, A., Ratajczak, K., Duralski, D., Piechota-Polanczyk, A. & Polanczyk, A., Thermal analysis of plastics used in the food industry. Materials (Basel)., 15(1): (2022).

Nasirtabrizi, M. H., Ziaei, Z. M., Jadid, A. P. & Fatin, L. Z., Synthesis and chemical modification of maleic anhydride copolymers with phthalimide groups. Int. J. Ind. Chem., 4(1): 11 (2013).

Gunawardene, O. H. P., Gunathilake, C., Amaraweera, S. M., Fernando, N. M. L., Wanninayaka, D. B., Manamperi, A., Kulatunga, A. K., et al., Compatibilization of starch/synthetic biodegradable polymer blends for packaging applications: A review. J. Compos. Sci., 5(11): 1–33 (2021).

Obasi, H. C. & Igwe, I. O., Cassava starch-mixed polypropylene bidegradable polymer: Preparation, characterization, and effect biodegradable products on growth of plants. Int. J. Sci. Res., 3(7): 802–807 (2012).

Tanjung, D. A., Jamarun, N., Arief, S., Aziz, H., Ritonga, A. H. & Isfa, B., Improving mechanical and physical properties on thermoplastic sago starch blends with the addition of polypropylene. Rasayan J. Chem., 14(4): 2451–2458 (2021).

Harsojuwono, B. A., Arnata, I. W., Hartiati, A., Setiyo, Y., Hatiningsih, S. & Suriati, L., The Improvement of the Modified Starch—Glucomannan—Polyvinyl Alcohol Biothermoplastic Composite Characteristics With Polycaprolactone and Anhydride Maleic Acid. Front. Sustain. Food Syst., 6(March): 1–13 (2022).

Widiarto, S. & Brojonegoro, J. S., EFFECT OF BORAX ON MECHANICAL PROPERTIES AND BIODEGRADABILITY OF SAGO STARCH - POLY ( VINYL ALCOHOL ) BLEND FrLMS. Polymers (Basel)., I(3): 151–157 (2005).

Pati, D. & Pisang, K., 3 ; 2 ; 69–81

Subramanian, N., Vinoth Kumar, B., Geetha, M. & Gladys Kalpana, K., Biodegradable Plastic From Mixed Starch. Int. J. Mech. Eng., 6(3): 1009–1019 (2021).

Coppola, G., Gaudio, M. T., Lopresto, C. G., Calabro, V., Curcio, S. & Chakraborty, S., Bioplastic from Renewable Biomass: A Facile Solution for a Greener Environment. Earth Syst. Environ., 5(2): 231–251 (2021).

Folino, A., Pangallo, D. & Calabrò, P. S., Assessing bioplastics biodegradability by standard and research methods: Current trends and open issues. J. Environ. Chem. Eng., 11(2): (2023).

Downloads

Published

2024-09-30

How to Cite

Dewi, R. ., Zulnazri, Z., Sylvia, N. ., & Riza, M. . (2024). Pengaruh Compatibilizer Polyvinyl Alcohol-graft-Maleic Anhydride (PVA-g-MAH) terhadap Karakteristik Plastik Degradable Berbasis Pati Sagu dan Pati Biji Nangka. Jurnal Riset Kimia, 15(2), 47–64. https://doi.org/10.25077/jrk.v15i2.695

Issue

Section

Articles

Citation Check