PENAMBAHAN ASAM OLEAT TERHADAP Sistem transpor Cu(II) dengan zat pembawa oksin melalui teknik membran cair fasa ruah
DOI:
https://doi.org/10.25077/jrk.v2i1.88Abstract
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ABSTRACT
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The removal of Cu(II) from aqueous solutions had been employed throught bulk liquid membrane techniques with arrange the optimization conditions of transport Cu(II) interface system. The optimum conditions of transport were found to be 3.1510-4 M of Cu(II) at pH 3  in the source phase,  17.510-4 M oxine dissolved into chloroform as membrane phase, 0,15 M H2SO4 as acceptor in  receiving phase, stirring rate was 340 rpm and  it was found that the transport of Cu(II) to receiving phase reached 97.41% during 6 hours. The effect of addition  oleat acid 1.57  10-3 M as surfactant  in membrane phase resulted a rapidly time of  transport Cu(II) to be 3 hours, wherein Cu(II) transported  into  the receive phase reached 97.83%  and remained  in feed phase 0%.
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Keywords: bulk liquid membrane, oxine, oleat acid, Cu(II) )transport
References
M. Mulder, Basic Principle of Membrane Technology, Kluwer Academic Publisher, Dordrecht, 1991, 244 – 259.
H. Alpoguz, Ahmed Kaya, Mehmed Karakus, Mechanism and Kinetics of Copper(II) Transport Through a Liquid Membrane Containing a Dithio phosphonate Derivative as Carrier, Turk. J. Chem., 29 : 345-353, (2005).
F. Khalil, and M. Shamsipur, Separation Study of Cadmium as CdI42- Through a Bulk Liquid Membrane Containing Ketoconazole and Oleaic Acid, Anal Sci., 21: 501-505, ( 2005).
G. Leon, Facilitated Transport of Cobalt Through Bulk Liquid Membranes Containg Diethylhexyl Phosphoric Acid, Desalination, 162 : 211-215, ( 2004).
M. D. Granado-Castro, M. D. Galindo-Riano, M. Garcia-Vargas, Model Eksperiments To Test The Use Of A Liquid Membrane For Separation And Preconcentration Of Copper From Natural Water, Anal. Chim. Acta, 506: 81-86, (2004).
H. Korkmaz, Ahmet and Mehmet, Mechanism and Kinetics of Cu(II) Transport Throught a Liquid Membrane Containing a Dithiophosphonate Derivative as Carrier, Turk. J. Chem., 29 : 345 – 353, (2005).
Z. Kahar, Mempelajari Peranan Oksin Sebagai Zat Pembawa Co(II) Antar Fasa (air-kloroform-air) Melalui Teknik Membran Cair Fasa Ruah, J. Kimia Andalas, 8(2), 29-33, (2002).
Z. Kahar, A. Alif, H. Aziz, dan Emriadi, Pengaruh ion Fe(III), Ni(II), Cu(II) Terhadap Transpor Co(II) Antar Fasa (air-kloroform-air) Melalui Teknik Membran Cair Fasa Ruah, J. Kimia Andalas, 8(1), 29-33, (2002).
Z. Kahar, Mempelajari Transpor Cd(II) Antar Fasa Untuk Teknik Pemisahan Melalui Membran Cair Fasa Ruah Dengan Menggunakan Oksin Sebagai Zat Pembawa, Laporan Penelitian Project TPSDP Research Grant Jurusan Kimia FMIPA Unand, 2005.
O. Norita, Transpor Antar Fasa dari Ion Tembaga (II) Melalui Membran Cair Fasa Ruah. Thesis Program Pascasarjana, Universitas Andalas, Padang, 2001.
Shirtin, Kinetika Transpor Cu(II) dengan Zat Pembawa Oksin dan Asam Oleat Sebagai Zat Aditif Melalui Teknik Membran Cair Fasa Ruah, Skripsi, Jurusan Kimia, Universitas Andalas, Padang, 2006.
Dean, Langer’s Handbook of Chemistry Ed 13 th . New York. 1985, 88-89.
Mellan, Organic Reagents in Anorganic Analysis. Wiley Erterm Limited, 1982, 31-108.
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