KINETIKA DAN SELEKTIFITAS SISTIM TRANSPOR Cu(II) ANTAR FASA MELALUI TEKNIK MEMBRAN CAIR FASA RUAH DENGAN MENGGUNAKAN OKSIN SEBAGAI ZAT PEMBAWA
DOI:
https://doi.org/10.25077/jrk.v4i1.89Abstract
Â
Â
ABSTRACT
The effect of addition oleat acid 1.575 × 10-4M into membrane phase had been employed at the optimum condition of Cu(II) transport by the composition Cu(II) 3.15 × 10-4M as source phase with pH 3, oxine 17.5 × 10-4M dissolved into chloroform as membrane phase, H2SO4 0.15 M as receiving phase, stirring rate was 340 rpm. The result of the research showed increase in effectivity of transport Cu(II) interphase from 6 hours to 3 hours with the rate constants into membrane phase extraction (k1) 0.0454 minute-1, the stripping (k2) 0.0364 minute-1 at the temperature of 301°K and activation energy (Ea) 51.147 Kj/mol. The reaction was identified by means of kinetic model involving two consecutive irreversible first order. The selectivity of Cu(II) transport system analyzed to mixed Cu(II) ion with Cd(II), Co(II), Ni(II), Mg(II), Ca(II) and Sr(II) ions in pairing system or totaly system in 1 : 1 comparison. The measurement was performed to each ions that was transported receiving phase and the remains in resource phase by using SSA model Alfa-4. The result of research showed that Cu(II) was selective enough transported.Â
Â
Keywords: Kinetic transportation, Cu(II) ions, oxine, oleat acid, selectivity
  ÂReferences
M. Mulder, Basic Principle of Membrane Technology, Kluwer Academic Publisher, Dordrecht, 1991, 244 – 259.
Stary, J. Anal. Chem. Ac. 28: 132 – 149, (1963).
H.K. Alpoguz, A. Kaya, M. Karakus, Mechanism and Kinetics of Copper(II) Transport Through a Liquid Membrane Containing a Dithiophosphonate Deri-vative as Carrier, Turk. J. Chem., 29: 345-353, (2005).
F. Khalil and M. Shamsipur, Separation Study of Cadmium as CdI42- Through a Bulk Liquid Membrane Containing Ketoconazole and Oleaic Acid, Anal. Sci., 21: 501-505, (2005).
G. Leon, Facilitated Transport of Cobalt (II) Through Bulk Liquid Membranes Containing Diethylhexyl Phosphoric Acid, Desalination, 162: 211-215, (2004).
M.D. Granado-Castro, M. D. Galindo-Riano, M Garcia-Vargas, Model Experiments to Test The Use of a Liquid Membrane For Separation and Preconcentration of Copper From Natural Water, Analytica Cimica Acta, 506: 81-86, (2004).
H. Korkmaz, Ahmet and Mehmet, Mechanism and Kinetics of Cu(II) Transport Throught a Liquid Membrane Containing a Dithiophosphonate Deri-vativeas Carrier, Turk. J. Chem., 29: 345 – 353, (2005).
O. Norita, A. Alif, H. Aziz dan Emriadi. Transpor Antar Fasa dari Ion Tembaga (II) Melalui Membran Cair Fasa Ruah, Program Pascasarjana, Universitas Andalas, Padang, 2001, 14-34.
A. Safavi, and E. Shams, Selective and Efficient Transport of Hg(II) Through Bulk Membrane Using Methyl Red as Carrier. J. Membr. Sci., 144: 37 – 43, (1998).
Z. Kahar, Mempelajari Peranan Oksin sebagai Zat Pembawa Co(II) Antar Fasa (air-kloroform-air) Melalui Teknik Membran Cair Fasa Ruah, Jurnal Kimia Andalas, 8(2): 29-33, (2002).
Z. Kahar, A. Alif, H. Aziz dan Emriadi, Pengaruh ion Fe(III), Ni(II), Cu(II) Terhadap Transpor Co(II) Antar Fasa (air-kloroform-air) Melalui Teknik Membran Cair Fasa Ruah, Jurnal Kimia Andalas, 8(1): 29-33, (2002).
Refinel, Z. Kahar dan Y. Sahirra, Pengaruh konsentrasi ion Ca(II), Mg(II) dan Sr(II) Terhadap Optimasi Transpor Cd(II) Dengan Zat Pembawa Oksin Melalui Membran Cair Fasa Ruah, Jurnal Kimia Andalas. 11(2): 16-22, (2005).
Shertin, Kinetika Transpor Cu(II) dengan Zat Pembawa Oksin dan Asam Oleat sebagai Zat Aditif Melalui Teknik Membran Cair Fasa Ruah, Skripsi, Jurusan Kimia Universitas Andalas. Padang, 2006, 16-22.
L. Longquan, W. Cheng, L. Yadong, Separation of Cobalt and Nickel by Emulsion Liquid Membrane With the Use of EDTA as Masking Reagent, J. Membr. Sci., 135: 173 – 177, (1997).
Refinel, Z. Kahar, Rahmayeni, Mofliarti, Optimasi Kestabilan Emulsi Sebagai Membran Cair Untuk Ekstraksi Fenol Dalam Air, J. Kimia Andalas, 5(2): 24-27, (1999).
Refinel, Z. Kahar, Pengaruh Ion Klorida Dan Nitrat Terhadap Pemisahan Senyawa Fenol Dalam Air Dengan Teknik Emulsi Membran Cair, J. Kimia Andalas. 6(2), 77-80, (2000).
Dingseng Hc*, Ming Ma. Zhenzhua Zhao, Transport of Cadmium Ions Through a Liquid Membranes ContainingAmine Extrctants as Carriers, J. Membr. Sci., 169: 53 – 59, (2000).
H. Parham, and M. Shamsipur, Selective Membrane Transport of Pb2+ ion by a Cooperative Carrier Composed of 18-Crown-6, Tetrabutylammonium Iodide and Palmitic Acid, J. Membr. Sci., 95: 21 – 27, (1994).
Dean, Langer’s Handbook of Chemistry Ed. 13th , New York, 1985, 88-89.
Downloads
Published
How to Cite
Issue
Section
Citation Check
License
Please find the rights and licenses in Jurnal Riset Kimia (J. Ris. Kim). By submitting the article/manuscript of the article, the author(s) agree with this policy. No specific document sign-off is required.
1. License
The use the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License.Â
2. Author(s)' Warranties
The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).
3. User Rights
Under the Creative Commons license, the journal permits users to copy, distribute, and display the material for any purpose. Users will also need to attribute authors and J. Ris. Kim on distributing works in the journal and other media of publications.
4. Rights of Authors
Authors retain all their rights to the published works, such as (but not limited to) the following rights;
- Copyright and other proprietary rights relating to the article, such as patent rights,
- The right to use the substance of the article in own future works, including lectures and books,
- The right to reproduce the article for own purposes,
- The right to self-archive the article,
- The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
5. Co-Authorship
If the article was jointly prepared by more than one author, any authors submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf, and agrees to inform his/her co-authors of the terms of this policy. J. Ris. Kim will not be held liable for anything that may arise due to the author(s) internal dispute. J. Ris. Kim will only communicate with the corresponding author.